Palladium‐Catalyzed Amination of Aryl Halides—Catalysts on New Routes to Known Targets

Matthias Beller

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

It's the base that matters! Sodium tert‐butoxide can be used to facilitate Pd‐catalyzed CN couplings directly with the amine. This was shown by research by Hartwig et al. and Buchwald et al. Thus, the use of ecologically unsound tin amides in the hetero‐Heck reaction may be avoided in future. Further improvement of the catalysts to make them industrially more interesting, and the extension of the method to CO couplings is eagerly awaited.

Original languageEnglish
Pages (from-to)1316-1317
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume34
Issue number12
DOIs
StatePublished - 7 Jul 1995
Externally publishedYes

Keywords

  • Heck reactions
  • aminations
  • arylamines
  • catalysis

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