Palladium complexes with bidentate P,N ligands: Synthesis, characterization and application in ethene oligomerization

Gabi Müller; Martti Klinga; Peter Osswald; Markku Leskelä; Bernhard Rieger

doi:10.1515/znb-2002-0713

Palladium complexes with bidentate P,N ligands: Synthesis, characterization and application in ethene oligomerization

Gabi Müller
, Martti Klinga
, Peter Osswald
, Markku Leskelä
, Bernhard Rieger

University of Ulm

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.

Original language	English
Pages (from-to)	803-809
Number of pages	7
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	57
Issue number	7
DOIs	https://doi.org/10.1515/znb-2002-0713
State	Published - 2002
Externally published	Yes

Keywords

Ethene Oligomerization
P,N Ligands
Palladium Complexes

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10.1515/znb-2002-0713

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title = "Palladium complexes with bidentate P,N ligands: Synthesis, characterization and application in ethene oligomerization",

abstract = "Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.",

keywords = "Ethene Oligomerization, P,N Ligands, Palladium Complexes",

author = "Gabi M{\"u}ller and Martti Klinga and Peter Osswald and Markku Leskel{\"a} and Bernhard Rieger",

note = "Funding Information: The Fonds der Chemischen Industrie and the DAAD are gratefully acknowledged for their financial support.",

year = "2002",

doi = "10.1515/znb-2002-0713",

language = "English",

volume = "57",

pages = "803--809",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "7",

}

TY - JOUR

T1 - Palladium complexes with bidentate P,N ligands

T2 - Synthesis, characterization and application in ethene oligomerization

AU - Müller, Gabi

AU - Klinga, Martti

AU - Osswald, Peter

AU - Leskelä, Markku

AU - Rieger, Bernhard

N1 - Funding Information: The Fonds der Chemischen Industrie and the DAAD are gratefully acknowledged for their financial support.

PY - 2002

Y1 - 2002

N2 - Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.

AB - Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.

KW - Ethene Oligomerization

KW - P,N Ligands

KW - Palladium Complexes

UR - https://www.scopus.com/pages/publications/0036060009

U2 - 10.1515/znb-2002-0713

DO - 10.1515/znb-2002-0713

M3 - Article

AN - SCOPUS:0036060009

SN - 0932-0776

VL - 57

SP - 803

EP - 809

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7

ER -

Palladium complexes with bidentate P,N ligands: Synthesis, characterization and application in ethene oligomerization

Abstract

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