Abstract
Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 803-809 |
| Number of pages | 7 |
| Journal | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences |
| Volume | 57 |
| Issue number | 7 |
| DOIs | |
| State | Published - 2002 |
| Externally published | Yes |
Keywords
- Ethene Oligomerization
- P,N Ligands
- Palladium Complexes