Palladium-catalyzed reductive carbonylation of aryl triflates with synthesis gas

Anne Brennfuhrer, Helfried Neumann, Matthias Beller

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

A general palladium-catalyzed reductive carbonylation of aryl triflates in the presence of synthesis gas (CO/H2) has been developed. The reaction with this most simple and environmentally benign formylation source proceeds under mild conditions and various aromatic aldehydes have been prepared in good to high yield.

Original languageEnglish
Pages (from-to)2537-2540
Number of pages4
JournalSynlett
Issue number16
DOIs
StatePublished - 1 Oct 2007
Externally publishedYes

Keywords

  • Aldehydes
  • Aryl triflates
  • Carbonylation
  • Homogenous catalysis
  • Palladium

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