Palladium-catalyzed reductive carbonylation of aryl bromides with phosphinite ligands

Helfried Neumann, Renat Kadyrov, Xiao Feng Wu, Matthias Beller

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

A palladium-catalyzed reductive carbonylation of aryl bromides into the corresponding aryl aldehydes has been described using synthesis gas in the presence of phosphinite ligands. Several products have been synthesized in moderate to good yields (35-97 %) under mild reaction conditions.

Original languageEnglish
Pages (from-to)2213-2216
Number of pages4
JournalChemistry - An Asian Journal
Volume7
Issue number10
DOIs
StatePublished - Oct 2012
Externally publishedYes

Keywords

  • aldehydes
  • aryl bromide
  • palladium
  • reductive carbonylation
  • synthesis gas

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