Oxygen reactivity and formate structure in X zeolite

M. Rep; J. G. Van Ommen; L. Lefferts; J. A. Lercher

doi:10.1016/s0167-2991(04)80549-4

Oxygen reactivity and formate structure in X zeolite

M. Rep, J. G. Van Ommen, L. Lefferts, J. A. Lercher

Chair of Chemical Technology II

University of Twente

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The i.r. absorption spectra of surface formate and gas phase decomposition products resulting from different surface reactions over basic FAU(X) zeolites have been compared. Based on these results a bridging surface formate species is proposed, which can account for the observed i.r. absorption data and different gas phase products.

Original language	English
Pages (from-to)	2745-2753
Number of pages	9
Journal	Studies in Surface Science and Catalysis
Volume	154 C
DOIs	https://doi.org/10.1016/s0167-2991(04)80549-4
State	Published - 2004

Keywords

Formaldehyde
Formate structure
Formic acid
Infrared
Methanol dehydrogenation
Oxygen

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10.1016/s0167-2991(04)80549-4

Cite this

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title = "Oxygen reactivity and formate structure in X zeolite",

abstract = "The i.r. absorption spectra of surface formate and gas phase decomposition products resulting from different surface reactions over basic FAU(X) zeolites have been compared. Based on these results a bridging surface formate species is proposed, which can account for the observed i.r. absorption data and different gas phase products.",

keywords = "Formaldehyde, Formate structure, Formic acid, Infrared, Methanol dehydrogenation, Oxygen",

author = "M. Rep and {Van Ommen}, {J. G.} and L. Lefferts and Lercher, {J. A.}",

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T1 - Oxygen reactivity and formate structure in X zeolite

AU - Rep, M.

AU - Van Ommen, J. G.

AU - Lefferts, L.

AU - Lercher, J. A.

PY - 2004

Y1 - 2004

N2 - The i.r. absorption spectra of surface formate and gas phase decomposition products resulting from different surface reactions over basic FAU(X) zeolites have been compared. Based on these results a bridging surface formate species is proposed, which can account for the observed i.r. absorption data and different gas phase products.

AB - The i.r. absorption spectra of surface formate and gas phase decomposition products resulting from different surface reactions over basic FAU(X) zeolites have been compared. Based on these results a bridging surface formate species is proposed, which can account for the observed i.r. absorption data and different gas phase products.

KW - Formaldehyde

KW - Formate structure

KW - Formic acid

KW - Infrared

KW - Methanol dehydrogenation

KW - Oxygen

UR - http://www.scopus.com/inward/record.url?scp=11844260040&partnerID=8YFLogxK

U2 - 10.1016/s0167-2991(04)80549-4

DO - 10.1016/s0167-2991(04)80549-4

M3 - Article

AN - SCOPUS:11844260040

SN - 0167-2991

VL - 154 C

SP - 2745

EP - 2753

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Oxygen reactivity and formate structure in X zeolite

Abstract

Keywords

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