Oxy Functionalization of Metal-Coordinated Heterocyclic Carbenes

Wolfgang A. Herrmann; Martina Elison; Georg Artus; Karl Öfele; Peter W. Roesky

doi:10.1021/om00003a003

Oxy Functionalization of Metal-Coordinated Heterocyclic Carbenes

Wolfgang A. Herrmann
, Martina Elison
, Georg Artus
, Karl Öfele
, Peter W. Roesky

Technical University of Munich

Technical University of Munich
Verband der Chemischen Industrie

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Metal-coordinated 1,3-dimethylimidazolin-2- ylidene ligands undergo osmylation by means of osmium tetraoxide to yield a new type of bimetallic, redox-stable complexes with metals in very different oxidation states (e.g. Cr⁰ / Os^VI). This oxy functionalization does not influence the metal-carbene bond in a significant way (IR and NMR spectra, single-crystal X-ray diffraction structure).

Original language	English
Pages (from-to)	1085-1086
Number of pages	2
Journal	Organometallics
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/om00003a003
State	Published - Mar 1995

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title = "Oxy Functionalization of Metal-Coordinated Heterocyclic Carbenes",

abstract = "Metal-coordinated 1,3-dimethylimidazolin-2- ylidene ligands undergo osmylation by means of osmium tetraoxide to yield a new type of bimetallic, redox-stable complexes with metals in very different oxidation states (e.g. Cr0 / OsVI). This oxy functionalization does not influence the metal-carbene bond in a significant way (IR and NMR spectra, single-crystal X-ray diffraction structure).",

author = "Herrmann, \{Wolfgang A.\} and Martina Elison and Georg Artus and Karl {\"O}fele and Roesky, \{Peter W.\}",

year = "1995",

month = mar,

doi = "10.1021/om00003a003",

language = "English",

volume = "14",

pages = "1085--1086",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - Oxy Functionalization of Metal-Coordinated Heterocyclic Carbenes

AU - Herrmann, Wolfgang A.

AU - Elison, Martina

AU - Artus, Georg

AU - Öfele, Karl

AU - Roesky, Peter W.

PY - 1995/3

Y1 - 1995/3

N2 - Metal-coordinated 1,3-dimethylimidazolin-2- ylidene ligands undergo osmylation by means of osmium tetraoxide to yield a new type of bimetallic, redox-stable complexes with metals in very different oxidation states (e.g. Cr0 / OsVI). This oxy functionalization does not influence the metal-carbene bond in a significant way (IR and NMR spectra, single-crystal X-ray diffraction structure).

AB - Metal-coordinated 1,3-dimethylimidazolin-2- ylidene ligands undergo osmylation by means of osmium tetraoxide to yield a new type of bimetallic, redox-stable complexes with metals in very different oxidation states (e.g. Cr0 / OsVI). This oxy functionalization does not influence the metal-carbene bond in a significant way (IR and NMR spectra, single-crystal X-ray diffraction structure).

UR - https://www.scopus.com/pages/publications/0001498394

U2 - 10.1021/om00003a003

DO - 10.1021/om00003a003

M3 - Article

AN - SCOPUS:0001498394

SN - 0276-7333

VL - 14

SP - 1085

EP - 1086

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Oxy Functionalization of Metal-Coordinated Heterocyclic Carbenes

Abstract

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