Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2

Hans H. Karsch; Brigitte Deubelly; Gerhard Müller

doi:10.1039/C39880000517

Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me ₃Si)₂C=PMe₂-PMe₂=C(SiMe ₃)₂

Hans H. Karsch
, Brigitte Deubelly
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Metal induced coupling of [CH₂PMe₂]^- leads to Me₂PCH₂CH₂PMe₂, whereas coupling of [C(X)(SiMe₃)(PMe₂)]^- (X=SiMe₃ or PMe₂) results in P-P bond formation affording [(X)(SiMe ₃)C=PMe₂-]₂, with a central P-P bond of length 2.278(1) Å.

Original language	English
Pages (from-to)	517-518
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39880000517
State	Published - 1988

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title = "Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2",

abstract = "Metal induced coupling of [CH2PMe2]- leads to Me2PCH2CH2PMe2, whereas coupling of [C(X)(SiMe3)(PMe2)]- (X=SiMe3 or PMe2) results in P-P bond formation affording [(X)(SiMe 3)C=PMe2-]2, with a central P-P bond of length 2.278(1) {\AA}.",

author = "Karsch, \{Hans H.\} and Brigitte Deubelly and Gerhard M{\"u}ller",

year = "1988",

doi = "10.1039/C39880000517",

language = "English",

pages = "517--518",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

}

Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me ₃Si)₂C=PMe₂-PMe₂=C(SiMe ₃)₂. / Karsch, Hans H.; Deubelly, Brigitte; Müller, Gerhard.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 1988, p. 517-518.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Oxidative coupling of phosphinomethanides at a metal centre

T2 - P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2

AU - Karsch, Hans H.

AU - Deubelly, Brigitte

AU - Müller, Gerhard

PY - 1988

Y1 - 1988

N2 - Metal induced coupling of [CH2PMe2]- leads to Me2PCH2CH2PMe2, whereas coupling of [C(X)(SiMe3)(PMe2)]- (X=SiMe3 or PMe2) results in P-P bond formation affording [(X)(SiMe 3)C=PMe2-]2, with a central P-P bond of length 2.278(1) Å.

AB - Metal induced coupling of [CH2PMe2]- leads to Me2PCH2CH2PMe2, whereas coupling of [C(X)(SiMe3)(PMe2)]- (X=SiMe3 or PMe2) results in P-P bond formation affording [(X)(SiMe 3)C=PMe2-]2, with a central P-P bond of length 2.278(1) Å.

UR - https://www.scopus.com/pages/publications/37049068532

U2 - 10.1039/C39880000517

DO - 10.1039/C39880000517

M3 - Article

AN - SCOPUS:37049068532

SN - 0022-4936

SP - 517

EP - 518

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Oxidative coupling of phosphinomethanides at a metal centre: P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me ₃Si)₂C=PMe₂-PMe₂=C(SiMe ₃)₂

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