TY - JOUR
T1 - Oxidative coupling of phosphinomethanides at a metal centre
T2 - P-P vs. C-C bond formation and the molecular structure of the novel bis-ylide (Me 3Si)2C=PMe2-PMe2=C(SiMe 3)2
AU - Karsch, Hans H.
AU - Deubelly, Brigitte
AU - Müller, Gerhard
PY - 1988
Y1 - 1988
N2 - Metal induced coupling of [CH2PMe2]- leads to Me2PCH2CH2PMe2, whereas coupling of [C(X)(SiMe3)(PMe2)]- (X=SiMe3 or PMe2) results in P-P bond formation affording [(X)(SiMe 3)C=PMe2-]2, with a central P-P bond of length 2.278(1) Å.
AB - Metal induced coupling of [CH2PMe2]- leads to Me2PCH2CH2PMe2, whereas coupling of [C(X)(SiMe3)(PMe2)]- (X=SiMe3 or PMe2) results in P-P bond formation affording [(X)(SiMe 3)C=PMe2-]2, with a central P-P bond of length 2.278(1) Å.
UR - http://www.scopus.com/inward/record.url?scp=37049068532&partnerID=8YFLogxK
U2 - 10.1039/C39880000517
DO - 10.1039/C39880000517
M3 - Article
AN - SCOPUS:37049068532
SN - 0022-4936
SP - 517
EP - 518
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 8
ER -