Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions

Yanmei Zhang; Ana M. Santos; Eberhardt Herdtweck; Janos Mink; Fritz E. Kühn

doi:10.1039/b414060e

Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions

Yanmei Zhang, Ana M. Santos, Eberhardt Herdtweck, Janos Mink, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Homogeneous catalytic processes mediated by silver(I) complexes are relatively rare. This work describes the synthesis and characterization of acetonitrile ligated silver salts with three weakly coordinating anions [B(C₆F₅)₄]^- [B{C₆H ₃(CF₃)₂}₄]^- and [(C ₆F₅)₃B-C₃H₄N ₂-B(C₆F₅)₃]^-. The silver cation is coordinated either by four or by two acetonitrile ligands. All examined Ag(I) complexes show catalytic activity in coupling reactions of terminal alkynes with aldehydes and amines.

Original language	English
Pages (from-to)	366-370
Number of pages	5
Journal	New Journal of Chemistry
Volume	29
Issue number	2
DOIs	https://doi.org/10.1039/b414060e
State	Published - Feb 2005

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title = "Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions",

abstract = "Homogeneous catalytic processes mediated by silver(I) complexes are relatively rare. This work describes the synthesis and characterization of acetonitrile ligated silver salts with three weakly coordinating anions [B(C6F5)4]- [B{C6H 3(CF3)2}4]- and [(C 6F5)3B-C3H4N 2-B(C6F5)3]-. The silver cation is coordinated either by four or by two acetonitrile ligands. All examined Ag(I) complexes show catalytic activity in coupling reactions of terminal alkynes with aldehydes and amines.",

author = "Yanmei Zhang and Santos, {Ana M.} and Eberhardt Herdtweck and Janos Mink and K{\"u}hn, {Fritz E.}",

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journal = "New Journal of Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions

AU - Zhang, Yanmei

AU - Santos, Ana M.

AU - Herdtweck, Eberhardt

AU - Mink, Janos

AU - Kühn, Fritz E.

PY - 2005/2

Y1 - 2005/2

N2 - Homogeneous catalytic processes mediated by silver(I) complexes are relatively rare. This work describes the synthesis and characterization of acetonitrile ligated silver salts with three weakly coordinating anions [B(C6F5)4]- [B{C6H 3(CF3)2}4]- and [(C 6F5)3B-C3H4N 2-B(C6F5)3]-. The silver cation is coordinated either by four or by two acetonitrile ligands. All examined Ag(I) complexes show catalytic activity in coupling reactions of terminal alkynes with aldehydes and amines.

AB - Homogeneous catalytic processes mediated by silver(I) complexes are relatively rare. This work describes the synthesis and characterization of acetonitrile ligated silver salts with three weakly coordinating anions [B(C6F5)4]- [B{C6H 3(CF3)2}4]- and [(C 6F5)3B-C3H4N 2-B(C6F5)3]-. The silver cation is coordinated either by four or by two acetonitrile ligands. All examined Ag(I) complexes show catalytic activity in coupling reactions of terminal alkynes with aldehydes and amines.

UR - http://www.scopus.com/inward/record.url?scp=14644387611&partnerID=8YFLogxK

U2 - 10.1039/b414060e

DO - 10.1039/b414060e

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SN - 1144-0546

VL - 29

SP - 366

EP - 370

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 2

ER -

Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions

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