Optical spectra of [formula omitted] and matrix effect upon its structure

N. Caspary; E. V. Savchenko; A. Thoma; A. Lammers; V. E. Bondybey

doi:10.1063/1.1312402

Optical spectra of [formula omitted] and matrix effect upon its structure

N. Caspary, E. V. Savchenko, A. Thoma, A. Lammers, V. E. Bondybey

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Abstract

Optical absorption and laser-induced fluorescence (LIF) spectra of [formula omitted] in solid matrices are investigated, and previous visible studies are extended into the infrared. Several new electronic states are observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase [formula omitted] photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for [formula omitted].

Original language	English
Pages (from-to)	744-751
Number of pages	8
Journal	Low Temperature Physics
Volume	26
Issue number	9
DOIs	https://doi.org/10.1063/1.1312402
State	Published - Sep 2000

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title = "Optical spectra of [formula omitted] and matrix effect upon its structure",

abstract = "Optical absorption and laser-induced fluorescence (LIF) spectra of [formula omitted] in solid matrices are investigated, and previous visible studies are extended into the infrared. Several new electronic states are observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase [formula omitted] photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for [formula omitted].",

author = "N. Caspary and Savchenko, {E. V.} and A. Thoma and A. Lammers and Bondybey, {V. E.}",

year = "2000",

month = sep,

doi = "10.1063/1.1312402",

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pages = "744--751",

journal = "Low Temperature Physics",

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T1 - Optical spectra of [formula omitted] and matrix effect upon its structure

AU - Caspary, N.

AU - Savchenko, E. V.

AU - Thoma, A.

AU - Lammers, A.

AU - Bondybey, V. E.

PY - 2000/9

Y1 - 2000/9

N2 - Optical absorption and laser-induced fluorescence (LIF) spectra of [formula omitted] in solid matrices are investigated, and previous visible studies are extended into the infrared. Several new electronic states are observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase [formula omitted] photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for [formula omitted].

AB - Optical absorption and laser-induced fluorescence (LIF) spectra of [formula omitted] in solid matrices are investigated, and previous visible studies are extended into the infrared. Several new electronic states are observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase [formula omitted] photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for [formula omitted].

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U2 - 10.1063/1.1312402

DO - 10.1063/1.1312402

M3 - Article

AN - SCOPUS:23044524915

SN - 1063-777X

VL - 26

SP - 744

EP - 751

JO - Low Temperature Physics

JF - Low Temperature Physics

IS - 9

ER -

Optical spectra of [formula omitted] and matrix effect upon its structure

Abstract

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