Optical spectra of CuO2 and matrix effect upon its structure

Nico Caspary; Elena V. Savchenko; Anton Thoma; Andreas Lammers; Vladimir E. Bondybey

Optical spectra of CuO₂ and matrix effect upon its structure

Nico Caspary
, Elena V. Savchenko
, Anton Thoma
, Andreas Lammers
, Vladimir E. Bondybey

Chair of Physical Chemistry

Infineon Technologies AG
B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine
Teradyne GmbH

Research output: Contribution to journal › Article › peer-review

Abstract

Optical absorption and laser induced fluorescence (LIF) spectra of CuO₂ in solid matrices have been investigated, and previous visible studies were extended into the infrared. Several new electronic states were observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase CuO^-₂ photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for CuO₂.

Original language	English
Pages (from-to)	1001-1010
Number of pages	10
Journal	Fizika Nizkikh Temperatur (Kharkov)
Volume	26
Issue number	9-10
State	Published - Sep 2000

Cite this

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title = "Optical spectra of CuO2 and matrix effect upon its structure",

abstract = "Optical absorption and laser induced fluorescence (LIF) spectra of CuO2 in solid matrices have been investigated, and previous visible studies were extended into the infrared. Several new electronic states were observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase CuO-2 photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for CuO2.",

author = "Nico Caspary and Savchenko, \{Elena V.\} and Anton Thoma and Andreas Lammers and Bondybey, \{Vladimir E.\}",

year = "2000",

month = sep,

language = "English",

volume = "26",

pages = "1001--1010",

journal = "Fizika Nizkikh Temperatur (Kharkov)",

issn = "0132-6414",

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TY - JOUR

T1 - Optical spectra of CuO2 and matrix effect upon its structure

AU - Caspary, Nico

AU - Savchenko, Elena V.

AU - Thoma, Anton

AU - Lammers, Andreas

AU - Bondybey, Vladimir E.

PY - 2000/9

Y1 - 2000/9

N2 - Optical absorption and laser induced fluorescence (LIF) spectra of CuO2 in solid matrices have been investigated, and previous visible studies were extended into the infrared. Several new electronic states were observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase CuO-2 photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for CuO2.

AB - Optical absorption and laser induced fluorescence (LIF) spectra of CuO2 in solid matrices have been investigated, and previous visible studies were extended into the infrared. Several new electronic states were observed and their vibrational frequencies determined. The matrix data are compared with the results of recent gas phase CuO-2 photodetachment studies, and with ab initio calculations. We also discuss the unusually large matrix effects and medium-induced electronic and vibrational frequency shifts observed for CuO2.

UR - https://www.scopus.com/pages/publications/0040568480

M3 - Article

AN - SCOPUS:0040568480

SN - 0132-6414

VL - 26

SP - 1001

EP - 1010

JO - Fizika Nizkikh Temperatur (Kharkov)

JF - Fizika Nizkikh Temperatur (Kharkov)

IS - 9-10

ER -

Optical spectra of CuO₂ and matrix effect upon its structure

Abstract

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