One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units

Mariusz Molon; Thomas Cadenbach; Timo Bollermann; Christian Gemel; Roland A. Fischer

doi:10.1039/c0cc00146e

One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From CpRh(GaCp)₂ to Cp*Rh(ZnR)₄ units

Mariusz Molon, Thomas Cadenbach, Timo Bollermann, Christian Gemel, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Two unusual compounds, [{Cp*Rh(ZnCp*)₂(ZnMe)(ZnCl)} ₂] (1) and [Cp*₂Rh][(Cp*Rh)₆Zn ₁₈Cl₁₂(μ₆-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn₄ building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)₂(GaCl₂Cp*)] with ZnMe ₂ (Cp* = pentamethylcyclopentadienyl).

Original language	English
Pages (from-to)	5677-5679
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	31
DOIs	https://doi.org/10.1039/c0cc00146e
State	Published - 21 Aug 2010
Externally published	Yes

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title = "One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units",

abstract = "Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn4 building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)2(GaCl2Cp*)] with ZnMe 2 (Cp* = pentamethylcyclopentadienyl).",

author = "Mariusz Molon and Thomas Cadenbach and Timo Bollermann and Christian Gemel and Fischer, {Roland A.}",

year = "2010",

month = aug,

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doi = "10.1039/c0cc00146e",

language = "English",

volume = "46",

pages = "5677--5679",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - One electron organozinc ligands in metal rich molecules by Ga/Zn exchange

T2 - From Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units

AU - Molon, Mariusz

AU - Cadenbach, Thomas

AU - Bollermann, Timo

AU - Gemel, Christian

AU - Fischer, Roland A.

PY - 2010/8/21

Y1 - 2010/8/21

N2 - Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn4 building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)2(GaCl2Cp*)] with ZnMe 2 (Cp* = pentamethylcyclopentadienyl).

AB - Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn4 building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)2(GaCl2Cp*)] with ZnMe 2 (Cp* = pentamethylcyclopentadienyl).

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U2 - 10.1039/c0cc00146e

DO - 10.1039/c0cc00146e

M3 - Article

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SN - 1359-7345

VL - 46

SP - 5677

EP - 5679

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From CpRh(GaCp)₂ to Cp*Rh(ZnR)₄ units

Abstract

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