On the vibrational structure in inner-shell ionization spectra by a many-body approach

W. Domcke, L. S. Cederbaum

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

The vibrational structure due to the ionization of inner-shell electrons is calculated for methane and carbon monoxide. The vibrational coupling constants are renormalized by going up to second order perturbation theory. It is found that for core electrons the renormalization is essential. The results are compared with experimental spectra.

Original languageEnglish
Pages (from-to)582-587
Number of pages6
JournalChemical Physics Letters
Volume31
Issue number3
DOIs
StatePublished - 15 Mar 1975

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