On the valence shell binding energy spectrum of carbonyl sulphide

J. P.D. Cook; M. G. White; C. E. Brion; W. Domcke; J. Schirmer; L. S. Cederbaum; W. von Niessen

doi:10.1016/0368-2048(81)85015-3

On the valence shell binding energy spectrum of carbonyl sulphide

J. P.D. Cook, M. G. White, C. E. Brion, W. Domcke, J. Schirmer, L. S. Cederbaum, W. von Niessen

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Abstract

The valence shell binding energy spectrum of carbonyl sulphide (10-45 eV) has been measured using both binary (e,2e) and dipole (e,2e) electron impact spectroscopy and calculated by the 2ph-TDA many body Green's function technique. The spectrum shows extensive structure above 20 eV, indicating a major breakdown of the quasi-particle picture for ionization of COS. The calculation is in good agreement with the present experimental and literature ESCA binding energy spectra. Binary (e,2e) spectra at two azimuthal angles support the theoretical prediction that this extensive final ion state structure arises primarily from ionization of the COS 6σ and 7σ inner valence electrons.

Original language	English
Pages (from-to)	261-270
Number of pages	10
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	22
Issue number	3
DOIs	https://doi.org/10.1016/0368-2048(81)85015-3
State	Published - 1981
Externally published	Yes

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title = "On the valence shell binding energy spectrum of carbonyl sulphide",

abstract = "The valence shell binding energy spectrum of carbonyl sulphide (10-45 eV) has been measured using both binary (e,2e) and dipole (e,2e) electron impact spectroscopy and calculated by the 2ph-TDA many body Green's function technique. The spectrum shows extensive structure above 20 eV, indicating a major breakdown of the quasi-particle picture for ionization of COS. The calculation is in good agreement with the present experimental and literature ESCA binding energy spectra. Binary (e,2e) spectra at two azimuthal angles support the theoretical prediction that this extensive final ion state structure arises primarily from ionization of the COS 6σ and 7σ inner valence electrons.",

author = "Cook, {J. P.D.} and White, {M. G.} and Brion, {C. E.} and W. Domcke and J. Schirmer and Cederbaum, {L. S.} and {von Niessen}, W.",

note = "Funding Information: Financial support for this work was provided by the Natural Sciences and Engmeermg Research Council of Canada.",

year = "1981",

doi = "10.1016/0368-2048(81)85015-3",

language = "English",

volume = "22",

pages = "261--270",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - On the valence shell binding energy spectrum of carbonyl sulphide

AU - Cook, J. P.D.

AU - White, M. G.

AU - Brion, C. E.

AU - Domcke, W.

AU - Schirmer, J.

AU - Cederbaum, L. S.

AU - von Niessen, W.

N1 - Funding Information: Financial support for this work was provided by the Natural Sciences and Engmeermg Research Council of Canada.

PY - 1981

Y1 - 1981

N2 - The valence shell binding energy spectrum of carbonyl sulphide (10-45 eV) has been measured using both binary (e,2e) and dipole (e,2e) electron impact spectroscopy and calculated by the 2ph-TDA many body Green's function technique. The spectrum shows extensive structure above 20 eV, indicating a major breakdown of the quasi-particle picture for ionization of COS. The calculation is in good agreement with the present experimental and literature ESCA binding energy spectra. Binary (e,2e) spectra at two azimuthal angles support the theoretical prediction that this extensive final ion state structure arises primarily from ionization of the COS 6σ and 7σ inner valence electrons.

AB - The valence shell binding energy spectrum of carbonyl sulphide (10-45 eV) has been measured using both binary (e,2e) and dipole (e,2e) electron impact spectroscopy and calculated by the 2ph-TDA many body Green's function technique. The spectrum shows extensive structure above 20 eV, indicating a major breakdown of the quasi-particle picture for ionization of COS. The calculation is in good agreement with the present experimental and literature ESCA binding energy spectra. Binary (e,2e) spectra at two azimuthal angles support the theoretical prediction that this extensive final ion state structure arises primarily from ionization of the COS 6σ and 7σ inner valence electrons.

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U2 - 10.1016/0368-2048(81)85015-3

DO - 10.1016/0368-2048(81)85015-3

M3 - Article

AN - SCOPUS:0010166498

SN - 0368-2048

VL - 22

SP - 261

EP - 270

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - 3

ER -

On the valence shell binding energy spectrum of carbonyl sulphide

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