On Chemical Problems of the Mechanism of Action of the Chlorothiobenzamides

Mifit Bahadir; Siegfried Nitz; Harun Parlar; Friedhelm Korte

doi:10.1021/jf60224a017

On Chemical Problems of the Mechanism of Action of the Chlorothiobenzamides

Mifit Bahadir
, Siegfried Nitz
, Harun Parlar
, Friedhelm Korte

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Both the direct and the photoinduced oxidation reactions of chlorine-substituted thiobenzamides (1b-3e) have been investigated. Asymmetric chlorophenylthiadiazoles (4b-4e) were identified as the principal transformation products. Oxidation of 2, 6-dichlorothiobenzamide (le) with nitrous acid unexpectedly afforded the corresponding 2, 6-dichlorophenyl mustard oil (3e), which has a strongly enhanced herbicidal action.

Original language	English
Pages (from-to)	815-818
Number of pages	4
Journal	Journal of agricultural and food chemistry
Volume	27
Issue number	4
DOIs	https://doi.org/10.1021/jf60224a017
State	Published - 1 Feb 1979

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10.1021/jf60224a017

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title = "On Chemical Problems of the Mechanism of Action of the Chlorothiobenzamides",

abstract = "Both the direct and the photoinduced oxidation reactions of chlorine-substituted thiobenzamides (1b-3e) have been investigated. Asymmetric chlorophenylthiadiazoles (4b-4e) were identified as the principal transformation products. Oxidation of 2, 6-dichlorothiobenzamide (le) with nitrous acid unexpectedly afforded the corresponding 2, 6-dichlorophenyl mustard oil (3e), which has a strongly enhanced herbicidal action.",

author = "Mifit Bahadir and Siegfried Nitz and Harun Parlar and Friedhelm Korte",

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AU - Bahadir, Mifit

AU - Nitz, Siegfried

AU - Parlar, Harun

AU - Korte, Friedhelm

PY - 1979/2/1

Y1 - 1979/2/1

N2 - Both the direct and the photoinduced oxidation reactions of chlorine-substituted thiobenzamides (1b-3e) have been investigated. Asymmetric chlorophenylthiadiazoles (4b-4e) were identified as the principal transformation products. Oxidation of 2, 6-dichlorothiobenzamide (le) with nitrous acid unexpectedly afforded the corresponding 2, 6-dichlorophenyl mustard oil (3e), which has a strongly enhanced herbicidal action.

AB - Both the direct and the photoinduced oxidation reactions of chlorine-substituted thiobenzamides (1b-3e) have been investigated. Asymmetric chlorophenylthiadiazoles (4b-4e) were identified as the principal transformation products. Oxidation of 2, 6-dichlorothiobenzamide (le) with nitrous acid unexpectedly afforded the corresponding 2, 6-dichlorophenyl mustard oil (3e), which has a strongly enhanced herbicidal action.

UR - https://www.scopus.com/pages/publications/33845560188

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DO - 10.1021/jf60224a017

M3 - Article

AN - SCOPUS:33845560188

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JO - Journal of agricultural and food chemistry

JF - Journal of agricultural and food chemistry

IS - 4

ER -

On Chemical Problems of the Mechanism of Action of the Chlorothiobenzamides

Abstract

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