Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids

Daniel Betz; Alexander Raith; Mirza Cokoja; Fritz E. Kühn

doi:10.1002/cssc.201000008

Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids

Daniel Betz
, Alexander Raith
, Mirza Cokoja
, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

Is that a finalansa? Different room temperature ionic liquids (RTILs) are examined as solvents in the biphasic epoxidation of selected olefins with the ansa compounds 1 and 2 as catalyst precursors. Turnover frequencies of up to 44?000 h-1 are reached and the catalyst can easily be separated and recycled.

Original language	English
Pages (from-to)	559-562
Number of pages	4
Journal	ChemSusChem
Volume	3
Issue number	5
DOIs	https://doi.org/10.1002/cssc.201000008
State	Published - May 2010

Keywords

Alkenes
Epoxidation
Homogeneous catalysis
Ionic liquids
Molybdenum

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10.1002/cssc.201000008

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title = "Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids",

abstract = "Is that a finalansa? Different room temperature ionic liquids (RTILs) are examined as solvents in the biphasic epoxidation of selected olefins with the ansa compounds 1 and 2 as catalyst precursors. Turnover frequencies of up to 44?000 h-1 are reached and the catalyst can easily be separated and recycled.",

keywords = "Alkenes, Epoxidation, Homogeneous catalysis, Ionic liquids, Molybdenum",

author = "Daniel Betz and Alexander Raith and Mirza Cokoja and K{\"u}hn, \{Fritz E.\}",

year = "2010",

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doi = "10.1002/cssc.201000008",

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journal = "ChemSusChem",

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T1 - Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids

AU - Betz, Daniel

AU - Raith, Alexander

AU - Cokoja, Mirza

AU - Kühn, Fritz E.

PY - 2010/5

Y1 - 2010/5

N2 - Is that a finalansa? Different room temperature ionic liquids (RTILs) are examined as solvents in the biphasic epoxidation of selected olefins with the ansa compounds 1 and 2 as catalyst precursors. Turnover frequencies of up to 44?000 h-1 are reached and the catalyst can easily be separated and recycled.

AB - Is that a finalansa? Different room temperature ionic liquids (RTILs) are examined as solvents in the biphasic epoxidation of selected olefins with the ansa compounds 1 and 2 as catalyst precursors. Turnover frequencies of up to 44?000 h-1 are reached and the catalyst can easily be separated and recycled.

KW - Alkenes

KW - Epoxidation

KW - Homogeneous catalysis

KW - Ionic liquids

KW - Molybdenum

UR - https://www.scopus.com/pages/publications/77955889512

U2 - 10.1002/cssc.201000008

DO - 10.1002/cssc.201000008

M3 - Article

C2 - 20391452

AN - SCOPUS:77955889512

SN - 1864-5631

VL - 3

SP - 559

EP - 562

JO - ChemSusChem

JF - ChemSusChem

IS - 5

ER -

Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids

Abstract

Keywords

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