Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds

Elisabeth Gross; Klaus Jörg; Klaus Fiederling; Axel Göttlein; Wolfgang Malisch; Roland Boese

doi:10.1002/anie.198407381

Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds

Elisabeth Gross
, Klaus Jörg
, Klaus Fiederling
, Axel Göttlein
, Wolfgang Malisch
, Roland Boese

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

The mild preparation of Mo  P‐ and W  P‐compounds has been achieved by base‐assisted dehydrohalogenation or deamination of phosphanes: M(X)P(Y)→MP + XY.The compound 2, R  H, obtained from 1 by this reaction principle, can be converted in a controlled way into metallacycles of the type 3 (X)  S, CH₂, Fe(CO)₄. (Figure Presented.)

Original language	English
Pages (from-to)	738-739
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	23
Issue number	9
DOIs	https://doi.org/10.1002/anie.198407381
State	Published - Sep 1984
Externally published	Yes

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title = "Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds",

abstract = "The mild preparation of Mo  P‐ and W  P‐compounds has been achieved by base‐assisted dehydrohalogenation or deamination of phosphanes: M(X)P(Y)→MP + XY.The compound 2, R  H, obtained from 1 by this reaction principle, can be converted in a controlled way into metallacycles of the type 3 (X)  S, CH2, Fe(CO)4. (Figure Presented.)",

author = "Elisabeth Gross and Klaus J{\"o}rg and Klaus Fiederling and Axel G{\"o}ttlein and Wolfgang Malisch and Roland Boese",

year = "1984",

month = sep,

doi = "10.1002/anie.198407381",

language = "English",

volume = "23",

pages = "738--739",

journal = "Angewandte Chemie International Edition in English",

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T1 - Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds

AU - Gross, Elisabeth

AU - Jörg, Klaus

AU - Fiederling, Klaus

AU - Göttlein, Axel

AU - Malisch, Wolfgang

AU - Boese, Roland

PY - 1984/9

Y1 - 1984/9

N2 - The mild preparation of Mo  P‐ and W  P‐compounds has been achieved by base‐assisted dehydrohalogenation or deamination of phosphanes: M(X)P(Y)→MP + XY.The compound 2, R  H, obtained from 1 by this reaction principle, can be converted in a controlled way into metallacycles of the type 3 (X)  S, CH2, Fe(CO)4. (Figure Presented.)

AB - The mild preparation of Mo  P‐ and W  P‐compounds has been achieved by base‐assisted dehydrohalogenation or deamination of phosphanes: M(X)P(Y)→MP + XY.The compound 2, R  H, obtained from 1 by this reaction principle, can be converted in a controlled way into metallacycles of the type 3 (X)  S, CH2, Fe(CO)4. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985532375

U2 - 10.1002/anie.198407381

DO - 10.1002/anie.198407381

M3 - Article

AN - SCOPUS:84985532375

SN - 0570-0833

VL - 23

SP - 738

EP - 739

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 9

ER -

Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds

Abstract

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