TY - JOUR
T1 - Novel Fulvalene Derivatives of Zirconium
T2 - A Facile Entry into Organozirconium(III) Chemistry
AU - Ashworth, Terence V.
AU - Agreda, Tomas Cuenca
AU - Herdtweck, Eberhardt
AU - Herrmann, Wolfgang A.
PY - 1986/3
Y1 - 1986/3
N2 - A universally modifiable new starting substance, the fulvalene ZrIII complex 1, is formed upon reaction of Cp2ZrCl2 and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)2(C5H4−C5H4)O], the oxidation product of 1. (Figure Presented.)
AB - A universally modifiable new starting substance, the fulvalene ZrIII complex 1, is formed upon reaction of Cp2ZrCl2 and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)2(C5H4−C5H4)O], the oxidation product of 1. (Figure Presented.)
UR - https://www.scopus.com/pages/publications/84985574498
U2 - 10.1002/anie.198602891
DO - 10.1002/anie.198602891
M3 - Article
AN - SCOPUS:84985574498
SN - 0570-0833
VL - 25
SP - 289
EP - 290
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -