Novel Fulvalene Derivatives of Zirconium: A Facile Entry into Organozirconium(III) Chemistry

Terence V. Ashworth; Tomas Cuenca Agreda; Eberhardt Herdtweck; Wolfgang A. Herrmann

doi:10.1002/anie.198602891

Novel Fulvalene Derivatives of Zirconium: A Facile Entry into Organozirconium(III) Chemistry

Terence V. Ashworth
, Tomas Cuenca Agreda
, Eberhardt Herdtweck
, Wolfgang A. Herrmann

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

A universally modifiable new starting substance, the fulvalene Zr^III complex 1, is formed upon reaction of Cp₂ZrCl₂ and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)₂(C₅H₄₋C₅H₄)O], the oxidation product of 1. (Figure Presented.)

Original language	English
Pages (from-to)	289-290
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	25
Issue number	3
DOIs	https://doi.org/10.1002/anie.198602891
State	Published - Mar 1986

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abstract = "A universally modifiable new starting substance, the fulvalene ZrIII complex 1, is formed upon reaction of Cp2ZrCl2 and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)2(C5H4−C5H4)O], the oxidation product of 1. (Figure Presented.)",

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AU - Agreda, Tomas Cuenca

AU - Herdtweck, Eberhardt

AU - Herrmann, Wolfgang A.

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N2 - A universally modifiable new starting substance, the fulvalene ZrIII complex 1, is formed upon reaction of Cp2ZrCl2 and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)2(C5H4−C5H4)O], the oxidation product of 1. (Figure Presented.)

AB - A universally modifiable new starting substance, the fulvalene ZrIII complex 1, is formed upon reaction of Cp2ZrCl2 and sodium amalgam. 1 is highly reactive, but nevertheless it can be isolated. The fulvalene ligand ensures that the secondary products are dinuclear, e.g. [(CpZrCl)2(C5H4−C5H4)O], the oxidation product of 1. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985574498

U2 - 10.1002/anie.198602891

DO - 10.1002/anie.198602891

M3 - Article

AN - SCOPUS:84985574498

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Novel Fulvalene Derivatives of Zirconium: A Facile Entry into Organozirconium(III) Chemistry

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