Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety

Wolfgang A. Herrmann; Ulrich Küsthardt; Manfred L. Ziegler; Thomas Zahn

doi:10.1002/anie.198508601

Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety

Wolfgang A. Herrmann, Ulrich Küsthardt, Manfred L. Ziegler, Thomas Zahn

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The ReO₃ group is retained during the [3+2] cycloaddition of diphenylketene to the trioxorhenium(VII) compound 1; the metallacycle 2 precipitates in the form of violet crystals. The reaction could be of use for the oxidation of CC multiple bond systems (R = C₆H₅). (Figure Presented.)

Original language	English
Pages (from-to)	860-861
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	24
Issue number	10
DOIs	https://doi.org/10.1002/anie.198508601
State	Published - Oct 1985

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title = "Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety",

abstract = "The ReO3 group is retained during the [3+2] cycloaddition of diphenylketene to the trioxorhenium(VII) compound 1; the metallacycle 2 precipitates in the form of violet crystals. The reaction could be of use for the oxidation of CC multiple bond systems (R = C6H5). (Figure Presented.)",

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year = "1985",

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AU - Zahn, Thomas

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AB - The ReO3 group is retained during the [3+2] cycloaddition of diphenylketene to the trioxorhenium(VII) compound 1; the metallacycle 2 precipitates in the form of violet crystals. The reaction could be of use for the oxidation of CC multiple bond systems (R = C6H5). (Figure Presented.)

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Novel CO Bond Formation via [3+2] Cycloaddition of Diphenylketene to a Dioxo Metal Moiety

Abstract

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