TY - JOUR
T1 - Novel acyclic carbene-substituted phospha-palladacycles
AU - Frey, Guido D.
AU - Herrmann, Wolfgang A.
PY - 2005/12/1
Y1 - 2005/12/1
N2 - Here, we report the synthesis of the first phospha-palladacycle substituted with an acyclic carbene. The reaction of bis(dialkyl)aminocarbenes with the very stable phospha-palladacycles leads to metastable η1-carbene complexes, which can be converted by intramolecular reduction to zero valent palladium complexes.
AB - Here, we report the synthesis of the first phospha-palladacycle substituted with an acyclic carbene. The reaction of bis(dialkyl)aminocarbenes with the very stable phospha-palladacycles leads to metastable η1-carbene complexes, which can be converted by intramolecular reduction to zero valent palladium complexes.
KW - Acyclic carbene complexes
KW - Phospha-palladacycle
UR - https://www.scopus.com/pages/publications/27744473031
U2 - 10.1016/j.jorganchem.2005.07.055
DO - 10.1016/j.jorganchem.2005.07.055
M3 - Article
AN - SCOPUS:27744473031
SN - 0022-328X
VL - 690
SP - 5876
EP - 5880
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 24-25
ER -