NHC-Stabilized Silyl-Substituted Chlorosilylene

Gizem Dübek, Franziska Hanusch, Shigeyoshi Inoue

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The first N-heterocyclic carbene (NHC) stabilized silyl-substituted chlorosilylene (1) was isolated via selective dehydrochlorination by NHC from silyl-based Si(IV) precursor tBu3SiSiHCl2. Compound 1 can form an iron chlorosilylene complex (2) with an iron carbonyl dimer and undergoes chloride/hydride metathesis to yield a stable NHC-silylene hydride borane adduct (3). Upon treatment with additional NHC, chlorosilylene 1 was converted into silyl-substituted silyliumylidene ions (4).

Original languageEnglish
Pages (from-to)15700-15704
Number of pages5
JournalInorganic Chemistry
Volume58
Issue number23
DOIs
StatePublished - 2 Dec 2019

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