Abstract
Spectral hole burning is observed for the OH stretching mode of HDO dissolved in D2O at 298 K after intense infrared excitation. Three spectral components are inferred from the transient band shapes and related to an icelike molecular environment and other hydrogen-bonding configurations. A population lifetime of T1=82 ps and an anharmonic frequency shift of 27020 cm-1 are measured.
| Original language | English |
|---|---|
| Pages (from-to) | 2092-2095 |
| Number of pages | 4 |
| Journal | Physical Review Letters |
| Volume | 66 |
| Issue number | 16 |
| DOIs | |
| State | Published - 1991 |
| Externally published | Yes |