New Organophosphorus Ligands: 1,1,2‐Tris(diphenylphosphanyl)cyclopropane and Its Derivatives

Hubert Schmidbaur, Stefan Manhart, Annette Schier

Research output: Contribution to journalComment/debate

4 Scopus citations

Abstract

Cyclopropanation of 1,1,2‐tris(diphenylphosphanyl)ethene with dimethylsulfonium methylide affords the title compound 1. The trifunctional phosphane is transformed into the trioxide 2 and trisulfide 3 by oxidation with hydrogen peroxide or elemental sulfur, respectively. With the tetrahydrofuran — borane complex the tris(phosphane—borane) 4 is obtained. The crystal structure of compound 1 has been determined by single‐crystal X‐ray diffraction.

Original languageEnglish
Pages (from-to)2259-2261
Number of pages3
JournalChemische Berichte
Volume126
Issue number10
DOIs
StatePublished - Oct 1993
Externally publishedYes

Keywords

  • Cyclopropane, phosphanyl‐substituted
  • Phosphane ligands
  • Phosphane oxide and sulfide
  • Phosphane—borane

Fingerprint

Dive into the research topics of 'New Organophosphorus Ligands: 1,1,2‐Tris(diphenylphosphanyl)cyclopropane and Its Derivatives'. Together they form a unique fingerprint.

Cite this