[(N, N', N"-Tricyclohexyl)-N"-cyclohexylcarbamoylguanidinium] Tetrachloroaurate(III) as a Product of the Reaction of Dicyclohexylcarbodiimide with HAuCl4 · aq

Wolfgang Schneider, Andreas Bauer, Hubert Schmidbaur

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Abstract

Reaction of tetrachloroauric(III) acid hydrate with dicyclohexylcarbodiimide (dcc) in dichloromethane in the presence of equimolar amounts of triethylamine leads to a complex reaction mixture. One of the components was shown by X-ray crystallography to be |(N, N', N"-tricyclohexyl)-N"-cyclohexylcarbamoylguanidinium] tetrachloroaurate(III) (1) which contains as a cation the addition product of dec with the corresponding urea.

Original languageEnglish
Pages (from-to)1152-1154
Number of pages3
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume52
Issue number9
DOIs
StatePublished - Sep 1997

Keywords

  • Dicyclohexylcarbodiimide
  • Guanidinium Salt
  • Tetrachloroauric(III) Acid Hydrate
  • X-Ray

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