TY - JOUR
T1 - N-Heterocyclic carbenes via abstraction of ammonia
T2 - ‘normal’ carbenes with ‘abnormal’ character
AU - Schaper, Lars Arne
AU - öfele, Karl
AU - Kadyrov, Renat
AU - Bechlars, Bettina
AU - Drees, Markus
AU - Cokoja, Mirza
AU - Herrmann, Wolfgang A.
AU - Kühn, Fritz E.
PY - 2012/3/21
Y1 - 2012/3/21
N2 - A new ammonia adduct of a N-heterocyclic carbene (NHC) has been isolated, which can be used as a reagent for the synthesis of transition metal carbene complexes. It represents the first example of a 1,2,3-triazolylidene with a 1,2,4-substitution pattern, thus opening a new subclass (‘normal’ 1,2,3-triazolylidenes) of sterically and electronically tunable NHCs.
AB - A new ammonia adduct of a N-heterocyclic carbene (NHC) has been isolated, which can be used as a reagent for the synthesis of transition metal carbene complexes. It represents the first example of a 1,2,3-triazolylidene with a 1,2,4-substitution pattern, thus opening a new subclass (‘normal’ 1,2,3-triazolylidenes) of sterically and electronically tunable NHCs.
UR - http://www.scopus.com/inward/record.url?scp=84859059634&partnerID=8YFLogxK
U2 - 10.1039/c2cc30611e
DO - 10.1039/c2cc30611e
M3 - Article
AN - SCOPUS:84859059634
SN - 1359-7345
VL - 48
SP - 3857
EP - 3859
JO - Chemical Communications
JF - Chemical Communications
IS - 32
ER -