N-heterocyclic carbenes of iridium(I): Ligand effects on the catalytic activity in transfer hydrogenation

Sandra C. Zinner; Christoph F. Rentzsch; Eberhardt Herdtweck; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1039/b906855d

N-heterocyclic carbenes of iridium(I): Ligand effects on the catalytic activity in transfer hydrogenation

Sandra C. Zinner, Christoph F. Rentzsch, Eberhardt Herdtweck, Wolfgang A. Herrmann, Fritz E. Kühn

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

New Ir-NHC complexes based on different heterocyclic moieties like imidazole, benzimidazole and imidazolidine are presented and tested in transfer hydrogenation catalysis. A broad range of steric and electronic properties of NHC ligands is covered to give an idea for catalyst design from the experimental point of view.

Original language	English
Pages (from-to)	7055-7062
Number of pages	8
Journal	Dalton Transactions
Issue number	35
DOIs	https://doi.org/10.1039/b906855d
State	Published - 2009

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title = "N-heterocyclic carbenes of iridium(I): Ligand effects on the catalytic activity in transfer hydrogenation",

abstract = "New Ir-NHC complexes based on different heterocyclic moieties like imidazole, benzimidazole and imidazolidine are presented and tested in transfer hydrogenation catalysis. A broad range of steric and electronic properties of NHC ligands is covered to give an idea for catalyst design from the experimental point of view.",

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T2 - Ligand effects on the catalytic activity in transfer hydrogenation

AU - Zinner, Sandra C.

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AU - Herdtweck, Eberhardt

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

PY - 2009

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AB - New Ir-NHC complexes based on different heterocyclic moieties like imidazole, benzimidazole and imidazolidine are presented and tested in transfer hydrogenation catalysis. A broad range of steric and electronic properties of NHC ligands is covered to give an idea for catalyst design from the experimental point of view.

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U2 - 10.1039/b906855d

DO - 10.1039/b906855d

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SN - 1477-9226

SP - 7055

EP - 7062

JO - Dalton Transactions

JF - Dalton Transactions

IS - 35

ER -

N-heterocyclic carbenes of iridium(I): Ligand effects on the catalytic activity in transfer hydrogenation

Abstract

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