N-Heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes

Wolfgang A. Herrmann; Gerhard M. Lobmaier; Martina Elison

doi:10.1016/0022-328X(96)06296-1

N-Heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes

Wolfgang A. Herrmann, Gerhard M. Lobmaier, Martina Elison

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Oxometal complexes of molybdenum and tungsten in high oxidation states form stable adducts with 1,3-dimethylimidazoline-2-ylidene (L) 1. The first 'carbene' complexes of molybdenum(VI) [MoO₂Cl(L)₃]Cl (3a) and tungsten(VI) WO₂Cl₂(L)₂ (4b) are reported.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	520
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(96)06296-1
State	Published - 9 Aug 1996

Keywords

Heterocyclic carbenes
Imidazoline-2-ylidene
Molybdenum(VI)
Tungsten(VI)

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10.1016/0022-328X(96)06296-1

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title = "N-Heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes",

abstract = "Oxometal complexes of molybdenum and tungsten in high oxidation states form stable adducts with 1,3-dimethylimidazoline-2-ylidene (L) 1. The first 'carbene' complexes of molybdenum(VI) [MoO2Cl(L)3]Cl (3a) and tungsten(VI) WO2Cl2(L)2 (4b) are reported.",

keywords = "Heterocyclic carbenes, Imidazoline-2-ylidene, Molybdenum(VI), Tungsten(VI)",

author = "Herrmann, {Wolfgang A.} and Lobmaier, {Gerhard M.} and Martina Elison",

year = "1996",

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language = "English",

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T1 - N-Heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes

AU - Herrmann, Wolfgang A.

AU - Lobmaier, Gerhard M.

AU - Elison, Martina

PY - 1996/8/9

Y1 - 1996/8/9

N2 - Oxometal complexes of molybdenum and tungsten in high oxidation states form stable adducts with 1,3-dimethylimidazoline-2-ylidene (L) 1. The first 'carbene' complexes of molybdenum(VI) [MoO2Cl(L)3]Cl (3a) and tungsten(VI) WO2Cl2(L)2 (4b) are reported.

AB - Oxometal complexes of molybdenum and tungsten in high oxidation states form stable adducts with 1,3-dimethylimidazoline-2-ylidene (L) 1. The first 'carbene' complexes of molybdenum(VI) [MoO2Cl(L)3]Cl (3a) and tungsten(VI) WO2Cl2(L)2 (4b) are reported.

KW - Heterocyclic carbenes

KW - Imidazoline-2-ylidene

KW - Molybdenum(VI)

KW - Tungsten(VI)

UR - http://www.scopus.com/inward/record.url?scp=0030576448&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(96)06296-1

DO - 10.1016/0022-328X(96)06296-1

M3 - Article

AN - SCOPUS:0030576448

SN - 0022-328X

VL - 520

SP - 231

EP - 234

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

N-Heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes

Abstract

Keywords

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