Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes

Wolfgang A. Herrmann; Peter W. Roesky; Mei Wang; Wolfgang Scherer

doi:10.1021/om00023a064

Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes

Wolfgang A. Herrmann, Peter W. Roesky, Mei Wang, Wolfgang Scherer

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Reaction of methyltrioxorhenium (MTO) (1) and triphenylphosphine in diethyl ether gives bis(triphenylphosphine)methyldioxorhenium(V)·MTO (3a), which was characterized by a single-crystal X-ray diffraction study (crystal data: space group Cc, a = 1393.5(4) pm, b = 1367.5(1) pm, c = 1928.0(5) pm, β = 102.67(1)°, Z = 4). An MTO molecule acts as an axial Lewis base ligand in this mixed-valence Re^V/Re^VII complex that is structurally composed of two trigonal bipyramids joined via an unsymmetrical, slightly bent oxo bridge ligand. Both phosphine ligands of the Re^V fragment are in trans positions to each other while the methyl and oxo groups occupy equatorial sites. 3a as well as bis(triphenylphosphine)trichlororhenium(V) (4) are used as catalysts for the olefination of aldehydes with diazoalkanes.

Original language	English
Pages (from-to)	4531-4535
Number of pages	5
Journal	Organometallics
Volume	13
Issue number	11
DOIs	https://doi.org/10.1021/om00023a064
State	Published - 1 Nov 1994

Access to Document

10.1021/om00023a064

Cite this

@article{3549d965ee83417d96ec8adac0e3242b,

title = "Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes",

abstract = "Reaction of methyltrioxorhenium (MTO) (1) and triphenylphosphine in diethyl ether gives bis(triphenylphosphine)methyldioxorhenium(V)·MTO (3a), which was characterized by a single-crystal X-ray diffraction study (crystal data: space group Cc, a = 1393.5(4) pm, b = 1367.5(1) pm, c = 1928.0(5) pm, β = 102.67(1)°, Z = 4). An MTO molecule acts as an axial Lewis base ligand in this mixed-valence ReV/ReVII complex that is structurally composed of two trigonal bipyramids joined via an unsymmetrical, slightly bent oxo bridge ligand. Both phosphine ligands of the ReV fragment are in trans positions to each other while the methyl and oxo groups occupy equatorial sites. 3a as well as bis(triphenylphosphine)trichlororhenium(V) (4) are used as catalysts for the olefination of aldehydes with diazoalkanes.",

author = "Herrmann, {Wolfgang A.} and Roesky, {Peter W.} and Mei Wang and Wolfgang Scherer",

year = "1994",

month = nov,

day = "1",

doi = "10.1021/om00023a064",

language = "English",

volume = "13",

pages = "4531--4535",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes

AU - Herrmann, Wolfgang A.

AU - Roesky, Peter W.

AU - Wang, Mei

AU - Scherer, Wolfgang

PY - 1994/11/1

Y1 - 1994/11/1

N2 - Reaction of methyltrioxorhenium (MTO) (1) and triphenylphosphine in diethyl ether gives bis(triphenylphosphine)methyldioxorhenium(V)·MTO (3a), which was characterized by a single-crystal X-ray diffraction study (crystal data: space group Cc, a = 1393.5(4) pm, b = 1367.5(1) pm, c = 1928.0(5) pm, β = 102.67(1)°, Z = 4). An MTO molecule acts as an axial Lewis base ligand in this mixed-valence ReV/ReVII complex that is structurally composed of two trigonal bipyramids joined via an unsymmetrical, slightly bent oxo bridge ligand. Both phosphine ligands of the ReV fragment are in trans positions to each other while the methyl and oxo groups occupy equatorial sites. 3a as well as bis(triphenylphosphine)trichlororhenium(V) (4) are used as catalysts for the olefination of aldehydes with diazoalkanes.

AB - Reaction of methyltrioxorhenium (MTO) (1) and triphenylphosphine in diethyl ether gives bis(triphenylphosphine)methyldioxorhenium(V)·MTO (3a), which was characterized by a single-crystal X-ray diffraction study (crystal data: space group Cc, a = 1393.5(4) pm, b = 1367.5(1) pm, c = 1928.0(5) pm, β = 102.67(1)°, Z = 4). An MTO molecule acts as an axial Lewis base ligand in this mixed-valence ReV/ReVII complex that is structurally composed of two trigonal bipyramids joined via an unsymmetrical, slightly bent oxo bridge ligand. Both phosphine ligands of the ReV fragment are in trans positions to each other while the methyl and oxo groups occupy equatorial sites. 3a as well as bis(triphenylphosphine)trichlororhenium(V) (4) are used as catalysts for the olefination of aldehydes with diazoalkanes.

UR - http://www.scopus.com/inward/record.url?scp=0001047456&partnerID=8YFLogxK

U2 - 10.1021/om00023a064

DO - 10.1021/om00023a064

M3 - Article

AN - SCOPUS:0001047456

SN - 0276-7333

VL - 13

SP - 4531

EP - 4535

JO - Organometallics

JF - Organometallics

IS - 11

ER -

Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this