Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes: Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V)

Wolfgang A. Herrmann; Monika U. Rauch; Peter W. Roesky

doi:10.1016/0022-328X(95)05928-I

Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes: Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V)

Wolfgang A. Herrmann
, Monika U. Rauch
, Peter W. Roesky

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Di(4-t-butylpyridine)dichloromethyloxorhenium(V) (1) is obtained by reductive halogenation of methyltrioxorhenium(VII) in the presence of t-butylpyridine. A number of new methylrhenium(V) complexes can be synthesized by substitution of the halide and/or pyridine ligands, e.g. with chelating N-and P-bases or Schiff base ligands. The new rhenium complexes exhibit an asymmetric coordination of the ligands.

Original language	English
Pages (from-to)	299-302
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	511
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05928-I
State	Published - 5 Apr 1996
Externally published	Yes

Keywords

Methylrhenium(V) oxo complexes
Rhenium
Schiff base ligands

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10.1016/0022-328X(95)05928-I

Cite this

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title = "Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes: Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V)",

abstract = "Di(4-t-butylpyridine)dichloromethyloxorhenium(V) (1) is obtained by reductive halogenation of methyltrioxorhenium(VII) in the presence of t-butylpyridine. A number of new methylrhenium(V) complexes can be synthesized by substitution of the halide and/or pyridine ligands, e.g. with chelating N-and P-bases or Schiff base ligands. The new rhenium complexes exhibit an asymmetric coordination of the ligands.",

keywords = "Methylrhenium(V) oxo complexes, Rhenium, Schiff base ligands",

author = "Herrmann, \{Wolfgang A.\} and Rauch, \{Monika U.\} and Roesky, \{Peter W.\}",

year = "1996",

month = apr,

day = "5",

doi = "10.1016/0022-328X(95)05928-I",

language = "English",

volume = "511",

pages = "299--302",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes: Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V). / Herrmann, Wolfgang A.; Rauch, Monika U.; Roesky, Peter W.
In: Journal of Organometallic Chemistry, Vol. 511, No. 1-2, 05.04.1996, p. 299-302.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes

T2 - Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V)

AU - Herrmann, Wolfgang A.

AU - Rauch, Monika U.

AU - Roesky, Peter W.

PY - 1996/4/5

Y1 - 1996/4/5

N2 - Di(4-t-butylpyridine)dichloromethyloxorhenium(V) (1) is obtained by reductive halogenation of methyltrioxorhenium(VII) in the presence of t-butylpyridine. A number of new methylrhenium(V) complexes can be synthesized by substitution of the halide and/or pyridine ligands, e.g. with chelating N-and P-bases or Schiff base ligands. The new rhenium complexes exhibit an asymmetric coordination of the ligands.

AB - Di(4-t-butylpyridine)dichloromethyloxorhenium(V) (1) is obtained by reductive halogenation of methyltrioxorhenium(VII) in the presence of t-butylpyridine. A number of new methylrhenium(V) complexes can be synthesized by substitution of the halide and/or pyridine ligands, e.g. with chelating N-and P-bases or Schiff base ligands. The new rhenium complexes exhibit an asymmetric coordination of the ligands.

KW - Methylrhenium(V) oxo complexes

KW - Rhenium

KW - Schiff base ligands

UR - https://www.scopus.com/pages/publications/0030569976

U2 - 10.1016/0022-328X(95)05928-I

DO - 10.1016/0022-328X(95)05928-I

M3 - Article

AN - SCOPUS:0030569976

SN - 0022-328X

VL - 511

SP - 299

EP - 302

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Multiple bonds between main group elements and transition metals, 154 methylrhenium(V) oxo complexes: Derivatives of di(4-t-butylpyridine) dichloromethyloxorhenium(V)

Abstract

Keywords

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