Monomeric phosphinoboranes: The role of the B- and P-substituents for P=B multiple bonding

Hans H. Karsch; Gerhard Hanika; Brigitte Huber; Klaus Meindl; Stephan König; Carl Krüger; Gerhard Müller

doi:10.1039/C39890000373

Monomeric phosphinoboranes: The role of the B- and P-substituents for P=B multiple bonding

Hans H. Karsch
, Gerhard Hanika
, Brigitte Huber
, Klaus Meindl
, Stephan König
, Carl Krüger
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The influence of the boron substituents on the structures of the first fully characterized monomeric diphosphinoboranes [(2,4,6-Me₃C ₆H₂)₂P]B-X (X = OEt, Br) has been established; especially for X = Br, P-B multiple bonding may be clearly inferred from the molecular structure.

Original language	English
Pages (from-to)	373-375
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39890000373
State	Published - 1989

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title = "Monomeric phosphinoboranes: The role of the B- and P-substituents for P=B multiple bonding",

abstract = "The influence of the boron substituents on the structures of the first fully characterized monomeric diphosphinoboranes [(2,4,6-Me3C 6H2)2P]B-X (X = OEt, Br) has been established; especially for X = Br, P-B multiple bonding may be clearly inferred from the molecular structure.",

author = "Karsch, \{Hans H.\} and Gerhard Hanika and Brigitte Huber and Klaus Meindl and Stephan K{\"o}nig and Carl Kr{\"u}ger and Gerhard M{\"u}ller",

year = "1989",

doi = "10.1039/C39890000373",

language = "English",

pages = "373--375",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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TY - JOUR

T1 - Monomeric phosphinoboranes

T2 - The role of the B- and P-substituents for P=B multiple bonding

AU - Karsch, Hans H.

AU - Hanika, Gerhard

AU - Huber, Brigitte

AU - Meindl, Klaus

AU - König, Stephan

AU - Krüger, Carl

AU - Müller, Gerhard

PY - 1989

Y1 - 1989

N2 - The influence of the boron substituents on the structures of the first fully characterized monomeric diphosphinoboranes [(2,4,6-Me3C 6H2)2P]B-X (X = OEt, Br) has been established; especially for X = Br, P-B multiple bonding may be clearly inferred from the molecular structure.

AB - The influence of the boron substituents on the structures of the first fully characterized monomeric diphosphinoboranes [(2,4,6-Me3C 6H2)2P]B-X (X = OEt, Br) has been established; especially for X = Br, P-B multiple bonding may be clearly inferred from the molecular structure.

UR - https://www.scopus.com/pages/publications/37049077637

U2 - 10.1039/C39890000373

DO - 10.1039/C39890000373

M3 - Article

AN - SCOPUS:37049077637

SN - 0022-4936

SP - 373

EP - 375

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

Monomeric phosphinoboranes: The role of the B- and P-substituents for P=B multiple bonding

Abstract

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