Molecular structure and solution behavior of a benzonitrile ligated silver(I) complex [Ag(PhCN)2][B(C6F5) 4]

Silvana F. Rach; Eberhardt Herdtweck; Fritz E. Kühn

doi:10.1002/zaac.201000408

Molecular structure and solution behavior of a benzonitrile ligated silver(I) complex [Ag(PhCN)₂][B(C₆F₅) ₄]

Silvana F. Rach, Eberhardt Herdtweck, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The bis(benzonitrile) complex [Ag(PhCN)₂][B(C₆F ₅)₄] is synthesized from its tetra(acetonitrile) ligated congener. X-ray diffraction studies were conducted to compare the bond lengths and angles of the complex in regard with those of other nitrile ligated silver cations with weakly coordinating anions. Vibrational spectra of the solid complex and in (concentrated) benzonitrile solution reveal differences in the strength of benzonitrile-silver ion interactions.

Original language	English
Pages (from-to)	499-501
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	637
Issue number	5
DOIs	https://doi.org/10.1002/zaac.201000408
State	Published - Apr 2011

Keywords

IR spectroscopy
Nitrile ligands
Silver
Weakly coordinating anions
X-ray diffraction

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abstract = "The bis(benzonitrile) complex [Ag(PhCN)2][B(C6F 5)4] is synthesized from its tetra(acetonitrile) ligated congener. X-ray diffraction studies were conducted to compare the bond lengths and angles of the complex in regard with those of other nitrile ligated silver cations with weakly coordinating anions. Vibrational spectra of the solid complex and in (concentrated) benzonitrile solution reveal differences in the strength of benzonitrile-silver ion interactions.",

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AU - Rach, Silvana F.

AU - Herdtweck, Eberhardt

AU - Kühn, Fritz E.

PY - 2011/4

Y1 - 2011/4

N2 - The bis(benzonitrile) complex [Ag(PhCN)2][B(C6F 5)4] is synthesized from its tetra(acetonitrile) ligated congener. X-ray diffraction studies were conducted to compare the bond lengths and angles of the complex in regard with those of other nitrile ligated silver cations with weakly coordinating anions. Vibrational spectra of the solid complex and in (concentrated) benzonitrile solution reveal differences in the strength of benzonitrile-silver ion interactions.

AB - The bis(benzonitrile) complex [Ag(PhCN)2][B(C6F 5)4] is synthesized from its tetra(acetonitrile) ligated congener. X-ray diffraction studies were conducted to compare the bond lengths and angles of the complex in regard with those of other nitrile ligated silver cations with weakly coordinating anions. Vibrational spectra of the solid complex and in (concentrated) benzonitrile solution reveal differences in the strength of benzonitrile-silver ion interactions.

KW - IR spectroscopy

KW - Nitrile ligands

KW - Silver

KW - Weakly coordinating anions

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=79953886312&partnerID=8YFLogxK

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DO - 10.1002/zaac.201000408

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SP - 499

EP - 501

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 5

ER -

Molecular structure and solution behavior of a benzonitrile ligated silver(I) complex [Ag(PhCN)₂][B(C₆F₅) ₄]

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Keywords

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