TY - JOUR
T1 - Molecular Siloxane Complexes of Rare Earth Metals—Model Systems for Silicate‐Supported Catalysts?
AU - Herrmann, Wolfgang A.
AU - Anwander, Reiner
AU - Dufaud, Veronique
AU - Scherer, Wolfgang
PY - 1994/6/6
Y1 - 1994/6/6
N2 - Participation of the oxygen atoms of the siloxane framework of ligand 1, and not only the terminal hydroxyl groups, may be required for the coordinative saturation of a metal center. This surprising conclusion was drawn from the X‐ray structure analysis of the first rare earth metal complex with this type of ligand. Compound 1 serves as a molecular model for SiO2 supports for transition metal catalysts. (Figure Presented.)
AB - Participation of the oxygen atoms of the siloxane framework of ligand 1, and not only the terminal hydroxyl groups, may be required for the coordinative saturation of a metal center. This surprising conclusion was drawn from the X‐ray structure analysis of the first rare earth metal complex with this type of ligand. Compound 1 serves as a molecular model for SiO2 supports for transition metal catalysts. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=0038231698&partnerID=8YFLogxK
U2 - 10.1002/anie.199412851
DO - 10.1002/anie.199412851
M3 - Article
AN - SCOPUS:0038231698
SN - 0570-0833
VL - 33
SP - 1285
EP - 1286
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -