Molecular Inorganic Silicon Chemistry: "Hypervalent" Molecules - Low-Valency Candidates for Materials?

Hans H. Karsch; Thomas Segmüller

doi:10.1002/9783527618224.ch2b

Molecular Inorganic Silicon Chemistry: "Hypervalent" Molecules - Low-Valency Candidates for Materials?

Hans H. Karsch, Thomas Segmüller

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Technical University of Munich

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

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Abstract

A series of silicon and germanium compounds with amidinate ligands have been synthesized and investigated spectroscopically and structurally. In contrast to silicon, germanium also forms stable compounds with amidinate ligands in the +2 valence state with remarkable stuctural features. Bis-anionic amidinate ligands at silicon centers provide bridging bonding modes which differ from those described in earlier reports.

Original language	English
Title of host publication	Organosilicon Chemistry VI
Subtitle of host publication	From Molecules to Materials
Publisher	Wiley-VCH Verlag GmbH
Pages	194-201
Number of pages	8
ISBN (Print)	3527312145, 9783527312146
DOIs	https://doi.org/10.1002/9783527618224.ch2b
State	Published - 21 May 2008

Keywords

Germanium amidinates
Hypervalency
Low-valency
Silicon amidinates

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10.1002/9783527618224.ch2b

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abstract = "A series of silicon and germanium compounds with amidinate ligands have been synthesized and investigated spectroscopically and structurally. In contrast to silicon, germanium also forms stable compounds with amidinate ligands in the +2 valence state with remarkable stuctural features. Bis-anionic amidinate ligands at silicon centers provide bridging bonding modes which differ from those described in earlier reports.",

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AU - Segmüller, Thomas

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Y1 - 2008/5/21

N2 - A series of silicon and germanium compounds with amidinate ligands have been synthesized and investigated spectroscopically and structurally. In contrast to silicon, germanium also forms stable compounds with amidinate ligands in the +2 valence state with remarkable stuctural features. Bis-anionic amidinate ligands at silicon centers provide bridging bonding modes which differ from those described in earlier reports.

AB - A series of silicon and germanium compounds with amidinate ligands have been synthesized and investigated spectroscopically and structurally. In contrast to silicon, germanium also forms stable compounds with amidinate ligands in the +2 valence state with remarkable stuctural features. Bis-anionic amidinate ligands at silicon centers provide bridging bonding modes which differ from those described in earlier reports.

KW - Germanium amidinates

KW - Hypervalency

KW - Low-valency

KW - Silicon amidinates

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M3 - Chapter

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BT - Organosilicon Chemistry VI

PB - Wiley-VCH Verlag GmbH

ER -

Molecular Inorganic Silicon Chemistry: "Hypervalent" Molecules - Low-Valency Candidates for Materials?

Abstract

Keywords

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