Molecular brass: Cu4Zn4, a ligand protected superatom cluster

Kerstin Freitag; Hung Banh; Christian Gemel; Rüdiger W. Seidel; Samia Kahlal; Jean Yves Saillard; Roland A. Fischer

doi:10.1039/c4cc03401e

Molecular brass: Cu₄Zn₄, a ligand protected superatom cluster

Kerstin Freitag
, Hung Banh
, Christian Gemel
, Rüdiger W. Seidel
, Samia Kahlal
, Jean Yves Saillard
, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu(CN^tBu)] with [Zn₂Cp*₂] yields [(CuCN^tBu)₄(ZnCp*)₄] (1a) and [(CuCN^tBu)₄(ZnCp*)₃(ZnCp)] (1b). According to DFT calculations, the [Cu₄Zn₄] unit fulfils the unified superatom model for cluster valence shell closing.

Original language	English
Pages (from-to)	8681-8684
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	63
DOIs	https://doi.org/10.1039/c4cc03401e
State	Published - 10 Jul 2014
Externally published	Yes

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title = "Molecular brass: Cu4Zn4, a ligand protected superatom cluster",

abstract = "The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu(CNtBu)] with [Zn2Cp*2] yields [(CuCNtBu)4(ZnCp*)4] (1a) and [(CuCNtBu)4(ZnCp*)3(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.",

author = "Kerstin Freitag and Hung Banh and Christian Gemel and Seidel, \{R{\"u}diger W.\} and Samia Kahlal and Saillard, \{Jean Yves\} and Fischer, \{Roland A.\}",

year = "2014",

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doi = "10.1039/c4cc03401e",

language = "English",

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journal = "Chemical Communications",

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TY - JOUR

T1 - Molecular brass

T2 - Cu4Zn4, a ligand protected superatom cluster

AU - Freitag, Kerstin

AU - Banh, Hung

AU - Gemel, Christian

AU - Seidel, Rüdiger W.

AU - Kahlal, Samia

AU - Saillard, Jean Yves

AU - Fischer, Roland A.

PY - 2014/7/10

Y1 - 2014/7/10

N2 - The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu(CNtBu)] with [Zn2Cp*2] yields [(CuCNtBu)4(ZnCp*)4] (1a) and [(CuCNtBu)4(ZnCp*)3(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.

AB - The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu(CNtBu)] with [Zn2Cp*2] yields [(CuCNtBu)4(ZnCp*)4] (1a) and [(CuCNtBu)4(ZnCp*)3(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.

UR - https://www.scopus.com/pages/publications/84904162538

U2 - 10.1039/c4cc03401e

DO - 10.1039/c4cc03401e

M3 - Article

AN - SCOPUS:84904162538

SN - 1359-7345

VL - 50

SP - 8681

EP - 8684

JO - Chemical Communications

JF - Chemical Communications

IS - 63

ER -

Molecular brass: Cu₄Zn₄, a ligand protected superatom cluster

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