MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis

Ralf Becker; Harish Parala; Frank Hipler; Olga P. Tkachenko; Konstantin V. Klementiev; Wolfgang Grünert; Hagen Wilmer; Olaf Hinrichsen; Martin Muhler; Alexander Birkner; Christof Wöll; Sven Schäfer; Roland A. Fischer

doi:10.1002/anie.200351166

MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis

Ralf Becker, Harish Parala, Frank Hipler, Olga P. Tkachenko, Konstantin V. Klementiev, Wolfgang Grünert, Hagen Wilmer, Olaf Hinrichsen, Martin Muhler, Alexander Birkner, Christof Wöll, Sven Schäfer, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu- and ZnO-containing methanol-synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route.

Original language	English
Pages (from-to)	2839-2842
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	43
Issue number	21
DOIs	https://doi.org/10.1002/anie.200351166
State	Published - 17 May 2004
Externally published	Yes

Keywords

CVD (chemical vapor deposition)
Copper
Heterogeneous catalysis
Mesoporous materials
Methanol synthesis
Zinc oxide

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10.1002/anie.200351166

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Becker, R., Parala, H., Hipler, F., Tkachenko, O. P., Klementiev, K. V., Grünert, W., Wilmer, H., Hinrichsen, O., Muhler, M., Birkner, A., Wöll, C., Schäfer, S., & Fischer, R. A. (2004). MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis. Angewandte Chemie International Edition in English, 43(21), 2839-2842. https://doi.org/10.1002/anie.200351166

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title = "MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis",

abstract = "Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu- and ZnO-containing methanol-synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route.",

keywords = "CVD (chemical vapor deposition), Copper, Heterogeneous catalysis, Mesoporous materials, Methanol synthesis, Zinc oxide",

author = "Ralf Becker and Harish Parala and Frank Hipler and Tkachenko, {Olga P.} and Klementiev, {Konstantin V.} and Wolfgang Gr{\"u}nert and Hagen Wilmer and Olaf Hinrichsen and Martin Muhler and Alexander Birkner and Christof W{\"o}ll and Sven Sch{\"a}fer and Fischer, {Roland A.}",

year = "2004",

month = may,

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doi = "10.1002/anie.200351166",

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Becker, R, Parala, H, Hipler, F, Tkachenko, OP, Klementiev, KV, Grünert, W, Wilmer, H, Hinrichsen, O, Muhler, M, Birkner, A, Wöll, C, Schäfer, S & Fischer, RA 2004, 'MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis', Angewandte Chemie International Edition in English, vol. 43, no. 21, pp. 2839-2842. https://doi.org/10.1002/anie.200351166

TY - JOUR

T1 - MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO

T2 - Supported catalysts for methanol synthesis

AU - Becker, Ralf

AU - Parala, Harish

AU - Hipler, Frank

AU - Tkachenko, Olga P.

AU - Klementiev, Konstantin V.

AU - Grünert, Wolfgang

AU - Wilmer, Hagen

AU - Hinrichsen, Olaf

AU - Muhler, Martin

AU - Birkner, Alexander

AU - Wöll, Christof

AU - Schäfer, Sven

AU - Fischer, Roland A.

PY - 2004/5/17

Y1 - 2004/5/17

N2 - Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu- and ZnO-containing methanol-synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route.

AB - Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu- and ZnO-containing methanol-synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route.

KW - CVD (chemical vapor deposition)

KW - Copper

KW - Heterogeneous catalysis

KW - Mesoporous materials

KW - Methanol synthesis

KW - Zinc oxide

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U2 - 10.1002/anie.200351166

DO - 10.1002/anie.200351166

M3 - Article

AN - SCOPUS:4544339211

SN - 1433-7851

VL - 43

SP - 2839

EP - 2842

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 21

ER -

MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO: Supported catalysts for methanol synthesis

Abstract

Keywords

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