Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

José M. López-De-Luzuriaga; Alexander Sladek; Hubert Schmidbaur

doi:10.1039/DT9960004511

Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

José M. López-De-Luzuriaga, Alexander Sladek, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh₃)₃]BF₄ afforded a dinuclear complex [Au₂(PPh₃)₃{SCH₂CH(OH)CH ₂OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.

Original language	English
Pages (from-to)	4511-4512
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	24
DOIs	https://doi.org/10.1039/DT9960004511
State	Published - 21 Dec 1996

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title = "Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol",

abstract = "Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh3)3]BF4 afforded a dinuclear complex [Au2(PPh3)3{SCH2CH(OH)CH 2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.",

author = "L{\'o}pez-De-Luzuriaga, {Jos{\'e} M.} and Alexander Sladek and Hubert Schmidbaur",

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T1 - Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

AU - López-De-Luzuriaga, José M.

AU - Sladek, Alexander

AU - Schmidbaur, Hubert

PY - 1996/12/21

Y1 - 1996/12/21

N2 - Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh3)3]BF4 afforded a dinuclear complex [Au2(PPh3)3{SCH2CH(OH)CH 2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.

AB - Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh3)3]BF4 afforded a dinuclear complex [Au2(PPh3)3{SCH2CH(OH)CH 2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.

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U2 - 10.1039/DT9960004511

DO - 10.1039/DT9960004511

M3 - Article

AN - SCOPUS:33748469790

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SP - 4511

EP - 4512

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 24

ER -

Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

Abstract

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