Mixed co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol

José M. López-De-Luzuriaga, Alexander Sladek, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Reaction of DL-3-sulfanylpropane-1,2-diol with [O(AuPPh3)3]BF4 afforded a dinuclear complex [Au2(PPh3)3{SCH2CH(OH)CH 2OH}] in which two gold environments, linear and trigonal planar, are present in the same molecule; the complex has been structurally characterized.

Original languageEnglish
Pages (from-to)4511-4512
Number of pages2
JournalJournal of the Chemical Society. Dalton Transactions
Issue number24
DOIs
StatePublished - 21 Dec 1996
Externally publishedYes

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