Mineralization routes to polyphosphides: Cu2P20 and Cu5InP16

Stefan Lange; Melanie Bawohl; Richard Weihrich; Tom Nilges

doi:10.1002/anie.200705540

Mineralization routes to polyphosphides: Cu₂P₂₀ and Cu₅InP₁₆

Stefan Lange, Melanie Bawohl, Richard Weihrich, Tom Nilges

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

(Figure Presented) Mineralization chemistry: Cu₂P₂₀ and Cu₅InP₁₆ were synthesized by a mineralization reaction from the elements and binary starting materials. Cu₂P₂₀ is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu₅InP ₁₆ displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges.

Original language	English
Pages (from-to)	5654-5657
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	47
Issue number	30
DOIs	https://doi.org/10.1002/anie.200705540
State	Published - 14 Jul 2008
Externally published	Yes

Keywords

Coinage metals
Indium
Mineralization reactions
Phosphorus
Polyphosphides

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title = "Mineralization routes to polyphosphides: Cu2P20 and Cu5InP16",

abstract = "(Figure Presented) Mineralization chemistry: Cu2P20 and Cu5InP16 were synthesized by a mineralization reaction from the elements and binary starting materials. Cu2P20 is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu5InP 16 displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges.",

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AU - Lange, Stefan

AU - Bawohl, Melanie

AU - Weihrich, Richard

AU - Nilges, Tom

PY - 2008/7/14

Y1 - 2008/7/14

N2 - (Figure Presented) Mineralization chemistry: Cu2P20 and Cu5InP16 were synthesized by a mineralization reaction from the elements and binary starting materials. Cu2P20 is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu5InP 16 displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges.

AB - (Figure Presented) Mineralization chemistry: Cu2P20 and Cu5InP16 were synthesized by a mineralization reaction from the elements and binary starting materials. Cu2P20 is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu5InP 16 displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges.

KW - Coinage metals

KW - Indium

KW - Mineralization reactions

KW - Phosphorus

KW - Polyphosphides

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DO - 10.1002/anie.200705540

M3 - Article

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Mineralization routes to polyphosphides: Cu₂P₂₀ and Cu₅InP₁₆

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Keywords

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