TY - JOUR
T1 - Methyltrioxorhenium(VII) as Catalyst for Epoxidations
T2 - Structure of the Active Species and Mechanism of Catalysis
AU - Herrmann, Wolfgang A.
AU - Fischer, Richard W.
AU - Scherer, Wolfgang
AU - Rauch, Monika U.
PY - 1993/8
Y1 - 1993/8
N2 - Explosive in the solid state, the bis(η2‐peroxo) complex 1, which in solution is the active species in the epoxidation of olefins with [CH3ReO3], could be characterized by X‐ray crystallography as the diglyme adduct 2. Under catalytic conditions (excess of H2O2), 1 is far more stable than in the free state. (Figure Presented.)
AB - Explosive in the solid state, the bis(η2‐peroxo) complex 1, which in solution is the active species in the epoxidation of olefins with [CH3ReO3], could be characterized by X‐ray crystallography as the diglyme adduct 2. Under catalytic conditions (excess of H2O2), 1 is far more stable than in the free state. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748224009&partnerID=8YFLogxK
U2 - 10.1002/anie.199311571
DO - 10.1002/anie.199311571
M3 - Article
AN - SCOPUS:33748224009
SN - 0570-0833
VL - 32
SP - 1157
EP - 1160
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 8
ER -