TY - JOUR
T1 - Methyltrioxorhenium as Catalyst for Olefin Metathesis
AU - Herrmann, Wolfgang A.
AU - Wagner, Werner
AU - Flessner, Uwe N.
AU - Volkhardt, Ursula
AU - Komber, Hartmut
PY - 1991/12
Y1 - 1991/12
N2 - No cocatalysts are needed as additives when methyltrioxorhenium (MTO) supported on acidic carriers is employed to catalyze the metathesis of functionalized olefins. A typical system is MTO/Al2O3−SiO2, which is active, for instance, in the metathesis of ally1 halides, allylsilanes, unsaturated carboxylates, and nitriles. MTO in combination with RnAlCl3‐n is a homogeneous catalyst in ring‐opening polymerizations (RCH3, C2H5; n = 1,2).
AB - No cocatalysts are needed as additives when methyltrioxorhenium (MTO) supported on acidic carriers is employed to catalyze the metathesis of functionalized olefins. A typical system is MTO/Al2O3−SiO2, which is active, for instance, in the metathesis of ally1 halides, allylsilanes, unsaturated carboxylates, and nitriles. MTO in combination with RnAlCl3‐n is a homogeneous catalyst in ring‐opening polymerizations (RCH3, C2H5; n = 1,2).
UR - http://www.scopus.com/inward/record.url?scp=33748347334&partnerID=8YFLogxK
U2 - 10.1002/anie.199116361
DO - 10.1002/anie.199116361
M3 - Article
AN - SCOPUS:33748347334
SN - 0570-0833
VL - 30
SP - 1636
EP - 1638
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -