TY - JOUR
T1 - Methylrhenium Oxides
T2 - Synthesis from R2O7 and Catalytic Activity in Olefin Metathesis
AU - Herrmann, Wolfgang A.
AU - Kuchler, Josef G.
AU - Felixberger, Josef K.
AU - Herdtweck, Eberhardt
AU - Wagner, Werner
PY - 1988/3
Y1 - 1988/3
N2 - Rhenium‐containing metathesis catalysts are formed selectively and in good yields from Re2O7 according to (a) and (b). In the presence of SnMe4, all four complexes are catalytically active, while in the absence of SnMe4 only 3, the methyl‐richest compound, still catalyzes the metathesis. 2 is the only diamagnetic compound in the series R6–2nReOn; this can be attributed to spin‐pairing in the ReRe bond. (Figure Presented.)
AB - Rhenium‐containing metathesis catalysts are formed selectively and in good yields from Re2O7 according to (a) and (b). In the presence of SnMe4, all four complexes are catalytically active, while in the absence of SnMe4 only 3, the methyl‐richest compound, still catalyzes the metathesis. 2 is the only diamagnetic compound in the series R6–2nReOn; this can be attributed to spin‐pairing in the ReRe bond. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84990101476&partnerID=8YFLogxK
U2 - 10.1002/anie.198803941
DO - 10.1002/anie.198803941
M3 - Article
AN - SCOPUS:84990101476
SN - 0570-0833
VL - 27
SP - 394
EP - 396
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -