Methylene‐Bridged Dinuclear Gold(III) Complexes with Terminal and Bridging Ylide Ligands

Hubert Schmidbaur; Christoph Hartmann

doi:10.1002/anie.198605751

Methylene‐Bridged Dinuclear Gold(_III) Complexes with Terminal and Bridging Ylide Ligands

Hubert Schmidbaur
, Christoph Hartmann

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Two exclusively C‐bonded gold atoms are present in the complex cation of 1, which, except for the bonds to the CH₂ bridge, only contains onium‐stabilized Au‐C bonds. The salt 1 may be converted reversibly into the corresponding ylide without isomerization of the ligands. (Figure Presented.)

Original language	English
Pages (from-to)	575-577
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	25
Issue number	6
DOIs	https://doi.org/10.1002/anie.198605751
State	Published - Jun 1986

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@article{2f7a99de31864c42bd9740f85a6dd128,

title = "Methylene‐Bridged Dinuclear Gold(III) Complexes with Terminal and Bridging Ylide Ligands",

abstract = "Two exclusively C‐bonded gold atoms are present in the complex cation of 1, which, except for the bonds to the CH2 bridge, only contains onium‐stabilized Au‐C bonds. The salt 1 may be converted reversibly into the corresponding ylide without isomerization of the ligands. (Figure Presented.)",

author = "Hubert Schmidbaur and Christoph Hartmann",

year = "1986",

month = jun,

doi = "10.1002/anie.198605751",

language = "English",

volume = "25",

pages = "575--577",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "6",

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T1 - Methylene‐Bridged Dinuclear Gold(III) Complexes with Terminal and Bridging Ylide Ligands

AU - Schmidbaur, Hubert

AU - Hartmann, Christoph

PY - 1986/6

Y1 - 1986/6

N2 - Two exclusively C‐bonded gold atoms are present in the complex cation of 1, which, except for the bonds to the CH2 bridge, only contains onium‐stabilized Au‐C bonds. The salt 1 may be converted reversibly into the corresponding ylide without isomerization of the ligands. (Figure Presented.)

AB - Two exclusively C‐bonded gold atoms are present in the complex cation of 1, which, except for the bonds to the CH2 bridge, only contains onium‐stabilized Au‐C bonds. The salt 1 may be converted reversibly into the corresponding ylide without isomerization of the ligands. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985609800

U2 - 10.1002/anie.198605751

DO - 10.1002/anie.198605751

M3 - Article

AN - SCOPUS:84985609800

SN - 0570-0833

VL - 25

SP - 575

EP - 577

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 6

ER -

Methylene‐Bridged Dinuclear Gold(_III) Complexes with Terminal and Bridging Ylide Ligands

Abstract

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