Metal@MOF: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition

Stephan Hermes; Marie Katrin Schröter; Rochus Schmid; Lamma Khodeir; Martin Muhler; Arno Tissler; Richard W. Fischer; Roland A. Fischer

doi:10.1002/anie.200462515

Metal@MOF: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition

Stephan Hermes, Marie Katrin Schröter, Rochus Schmid, Lamma Khodeir, Martin Muhler, Arno Tissler, Richard W. Fischer, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

652 Scopus citations

Abstract

Precursors and particles captured in a net: Porous coordination polymers such as MOF-5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η⁵-C₅H₅)Pd(η-C₃H ₅)]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described.

Original language	English
Pages (from-to)	6237-6241
Number of pages	5
Journal	Angewandte Chemie International Edition in English
Volume	44
Issue number	38
DOIs	https://doi.org/10.1002/anie.200462515
State	Published - 26 Sep 2005
Externally published	Yes

Keywords

Chemical vapor deposition
Coordination polymers
Heterogeneous catalysis
Methanol synthesis
Nanoparticles

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10.1002/anie.200462515

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abstract = "Precursors and particles captured in a net: Porous coordination polymers such as MOF-5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η5-C5H5)Pd(η-C3H 5)]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described.",

keywords = "Chemical vapor deposition, Coordination polymers, Heterogeneous catalysis, Methanol synthesis, Nanoparticles",

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AU - Hermes, Stephan

AU - Schröter, Marie Katrin

AU - Schmid, Rochus

AU - Khodeir, Lamma

AU - Muhler, Martin

AU - Tissler, Arno

AU - Fischer, Richard W.

AU - Fischer, Roland A.

PY - 2005/9/26

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AB - Precursors and particles captured in a net: Porous coordination polymers such as MOF-5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η5-C5H5)Pd(η-C3H 5)]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described.

KW - Chemical vapor deposition

KW - Coordination polymers

KW - Heterogeneous catalysis

KW - Methanol synthesis

KW - Nanoparticles

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JO - Angewandte Chemie International Edition in English

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IS - 38

ER -

Metal@MOF: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition

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Keywords

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