Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN4‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten

Wolfgang A. Herrmann; Norbert W. Huber; Peter Härter; Michael Denk; Florian Dyckhoff

doi:10.1002/cber.19921250119

Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN₄‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten

Wolfgang A. Herrmann, Norbert W. Huber, Peter Härter, Michael Denk, Florian Dyckhoff

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Multiple Bonds between Main‐Group Elements and Transition Metals, CII¹. — Volatile MN₄ Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl Substituents Niobium and tantalum complexes 4a and 4b of formula (Me₂SiH)N=M[N(SiHMe₂)₂]₃ (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl₃ (2a,b) or MCl₅ (3a,b). No β‐hydrogen decomposition of these compounds occurs under normal conditions.

Original language	German
Pages (from-to)	117-118
Number of pages	2
Journal	Chemische Berichte
Volume	125
Issue number	1
DOIs	https://doi.org/10.1002/cber.19921250119
State	Published - Jan 1992

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title = "Mehrfachbindungen zwischen Hauptgruppenelementen und {\"u}bergangsmetallen, CII. Fl{\"u}chtige MN4‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten",

abstract = "Multiple Bonds between Main‐Group Elements and Transition Metals, CII1. — Volatile MN4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl Substituents Niobium and tantalum complexes 4a and 4b of formula (Me2SiH)N=M[N(SiHMe2)2]3 (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl3 (2a,b) or MCl5 (3a,b). No β‐hydrogen decomposition of these compounds occurs under normal conditions.",

keywords = "Amido ligands, Imido ligands, Niobium complexes, Tantalum complexes",

author = "Herrmann, {Wolfgang A.} and Huber, {Norbert W.} and Peter H{\"a}rter and Michael Denk and Florian Dyckhoff",

year = "1992",

month = jan,

doi = "10.1002/cber.19921250119",

language = "Deutsch",

volume = "125",

pages = "117--118",

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T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN4‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten

AU - Herrmann, Wolfgang A.

AU - Huber, Norbert W.

AU - Härter, Peter

AU - Denk, Michael

AU - Dyckhoff, Florian

PY - 1992/1

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N2 - Multiple Bonds between Main‐Group Elements and Transition Metals, CII1. — Volatile MN4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl Substituents Niobium and tantalum complexes 4a and 4b of formula (Me2SiH)N=M[N(SiHMe2)2]3 (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl3 (2a,b) or MCl5 (3a,b). No β‐hydrogen decomposition of these compounds occurs under normal conditions.

AB - Multiple Bonds between Main‐Group Elements and Transition Metals, CII1. — Volatile MN4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl Substituents Niobium and tantalum complexes 4a and 4b of formula (Me2SiH)N=M[N(SiHMe2)2]3 (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl3 (2a,b) or MCl5 (3a,b). No β‐hydrogen decomposition of these compounds occurs under normal conditions.

KW - Amido ligands

KW - Imido ligands

KW - Niobium complexes

KW - Tantalum complexes

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DO - 10.1002/cber.19921250119

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Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN4‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten

Abstract

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Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen, CII. Flüchtige MN₄‐Metallkomplexe von Niob und Tantal mit Dimethylsilyl‐Substituenten