Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen: CLXVI.1 Molekulare Organorhenium-Vorstufen für CVD-prozesse

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Abstract

Under TG/MS conditions only the organorhenium (VII) trioxides CH3ReO3 and C2H5ReO3 sublime completely and without preliminary redox reactions. Choosing the right temperature conditions and organorhenium precursors in thermal CVD leads to layers containing only Re or ReOx (x=1-3) or ReCy (y<8.5).

Original languageEnglish
Pages (from-to)443-452
Number of pages10
JournalJournal of Organometallic Chemistry
Volume553
Issue number1-2
DOIs
StatePublished - 25 Feb 1998

Keywords

  • Alkyl
  • Aryl
  • CVD
  • Rhenium
  • Thermogravimetry

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