Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden

Wolfgang A. Herrmann; Michael Denk; Florian Dyckhoff; Joachim Behm

doi:10.1002/cber.19911241104

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden

Wolfgang A. Herrmann
, Michael Denk
, Florian Dyckhoff
, Joachim Behm

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Multiple Bonds Between Main‐Group Elements and Transition Metals, XCVI. – Niobium and Tantalum Complexes Having Imido Ligands The new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe₃)₂]₂(NSiMe₃)(OSiMe₃) (M = Nb, b; Ta, c) are accessible by the reaction of the oxychlorides MOCl₃ with the lithium amide LiN[Si(CH₃)₃]₂ in 36 and 27% isolated yield, respectively.

Original language	German
Pages (from-to)	2401-2404
Number of pages	4
Journal	Chemische Berichte
Volume	124
Issue number	11
DOIs	https://doi.org/10.1002/cber.19911241104
State	Published - Nov 1991

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title = "Mehrfachbindungen zwischen Hauptgruppenelementen und {\"U}bergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden",

abstract = "Multiple Bonds Between Main‐Group Elements and Transition Metals, XCVI. – Niobium and Tantalum Complexes Having Imido Ligands The new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe3)2]2(NSiMe3)(OSiMe3) (M = Nb, b; Ta, c) are accessible by the reaction of the oxychlorides MOCl3 with the lithium amide LiN[Si(CH3)3]2 in 36 and 27\% isolated yield, respectively.",

keywords = "NMR, O, Niobium complexes, Siloxy group, Silylamide, Silylimide, Tantalum complexes",

author = "Herrmann, \{Wolfgang A.\} and Michael Denk and Florian Dyckhoff and Joachim Behm",

year = "1991",

month = nov,

doi = "10.1002/cber.19911241104",

language = "Deutsch",

volume = "124",

pages = "2401--2404",

journal = "Chemische Berichte",

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publisher = "American Chemical Society",

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T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden

AU - Herrmann, Wolfgang A.

AU - Denk, Michael

AU - Dyckhoff, Florian

AU - Behm, Joachim

PY - 1991/11

Y1 - 1991/11

N2 - Multiple Bonds Between Main‐Group Elements and Transition Metals, XCVI. – Niobium and Tantalum Complexes Having Imido Ligands The new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe3)2]2(NSiMe3)(OSiMe3) (M = Nb, b; Ta, c) are accessible by the reaction of the oxychlorides MOCl3 with the lithium amide LiN[Si(CH3)3]2 in 36 and 27% isolated yield, respectively.

AB - Multiple Bonds Between Main‐Group Elements and Transition Metals, XCVI. – Niobium and Tantalum Complexes Having Imido Ligands The new niobium and tantalum complexes 2b and 2c of formula M[N(SiMe3)2]2(NSiMe3)(OSiMe3) (M = Nb, b; Ta, c) are accessible by the reaction of the oxychlorides MOCl3 with the lithium amide LiN[Si(CH3)3]2 in 36 and 27% isolated yield, respectively.

KW - NMR, O

KW - Niobium complexes

KW - Siloxy group

KW - Silylamide

KW - Silylimide

KW - Tantalum complexes

UR - https://www.scopus.com/pages/publications/0008052615

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DO - 10.1002/cber.19911241104

M3 - Artikel

AN - SCOPUS:0008052615

SN - 0009-2940

VL - 124

SP - 2401

EP - 2404

JO - Chemische Berichte

JF - Chemische Berichte

IS - 11

ER -

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, XCVI Niob‐ und Tantalkomplexe mit Imido‐Liganden

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