Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen CXLVIII. Alkinylrhenium(VII)-oxide-Synthese, eigenschaften und abbaureaktionen

Wolfgang A. Herrmann; Fritz E. Kühn; Carlos C. Romão

doi:10.1016/0022-328X(95)05456-Y

Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen CXLVIII. Alkinylrhenium(VII)-oxide-Synthese, eigenschaften und abbaureaktionen

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Alkinylrhenium(VII) oxides are synthesized from Re₂O₇ and alkinyltris(n-butyl)tin. They are moisture- and temperature-sensitive compounds. The organic ligand adopts η¹-coordination. Alkinylrhenium(VII) oxides can be stabilized by Lewis bases such as 2,2′-bipyridine. The resulting adducts are stable at room temperature. The decomposition of the title compounds depends on the concentration.

Original language	English
Pages (from-to)	209-213
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	495
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05456-Y
State	Published - 14 Jun 1995

Keywords

Alkinylrhenium(VII)-oxide
Decomposition
NMR spectroscopy
Rhenium
Synthesis

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10.1016/0022-328X(95)05456-Y

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@article{14871c403de54f05bfd60d4063e96bf3,

title = "Mehrfachbindungen zwischen Hauptgruppenelementen und {\"u}bergangsmetallen CXLVIII. Alkinylrhenium(VII)-oxide-Synthese, eigenschaften und abbaureaktionen",

abstract = "Alkinylrhenium(VII) oxides are synthesized from Re2O7 and alkinyltris(n-butyl)tin. They are moisture- and temperature-sensitive compounds. The organic ligand adopts η1-coordination. Alkinylrhenium(VII) oxides can be stabilized by Lewis bases such as 2,2′-bipyridine. The resulting adducts are stable at room temperature. The decomposition of the title compounds depends on the concentration.",

keywords = "Alkinylrhenium(VII)-oxide, Decomposition, NMR spectroscopy, Rhenium, Synthesis",

author = "Herrmann, \{Wolfgang A.\} and K{\"u}hn, \{Fritz E.\} and Rom{\~a}o, \{Carlos C.\}",

year = "1995",

month = jun,

day = "14",

doi = "10.1016/0022-328X(95)05456-Y",

language = "English",

volume = "495",

pages = "209--213",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen CXLVIII. Alkinylrhenium(VII)-oxide-Synthese, eigenschaften und abbaureaktionen

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

AU - Romão, Carlos C.

PY - 1995/6/14

Y1 - 1995/6/14

N2 - Alkinylrhenium(VII) oxides are synthesized from Re2O7 and alkinyltris(n-butyl)tin. They are moisture- and temperature-sensitive compounds. The organic ligand adopts η1-coordination. Alkinylrhenium(VII) oxides can be stabilized by Lewis bases such as 2,2′-bipyridine. The resulting adducts are stable at room temperature. The decomposition of the title compounds depends on the concentration.

AB - Alkinylrhenium(VII) oxides are synthesized from Re2O7 and alkinyltris(n-butyl)tin. They are moisture- and temperature-sensitive compounds. The organic ligand adopts η1-coordination. Alkinylrhenium(VII) oxides can be stabilized by Lewis bases such as 2,2′-bipyridine. The resulting adducts are stable at room temperature. The decomposition of the title compounds depends on the concentration.

KW - Alkinylrhenium(VII)-oxide

KW - Decomposition

KW - NMR spectroscopy

KW - Rhenium

KW - Synthesis

UR - https://www.scopus.com/pages/publications/0039669019

U2 - 10.1016/0022-328X(95)05456-Y

DO - 10.1016/0022-328X(95)05456-Y

M3 - Article

AN - SCOPUS:0039669019

SN - 0022-328X

VL - 495

SP - 209

EP - 213

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Mehrfachbindungen zwischen Hauptgruppenelementen und übergangsmetallen CXLVIII. Alkinylrhenium(VII)-oxide-Synthese, eigenschaften und abbaureaktionen

Abstract

Keywords

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