TY - JOUR
T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen. CX 1 1 CIX. Mitteilung siehe Ref. l.. Methylierte Nitridomolybdän(VI)-Komplexe
AU - Herrmann, Wolfgang A.
AU - Bogdanović, Sandra
AU - Behm, Joachim
AU - Denk, Michael
PY - 1992/6/6
Y1 - 1992/6/6
N2 - Methylation of the nitridomolybdenum(VI) complex NMo(O-t-C4H9)3 2, obtained from NMoCl3· THF (1), is achieved by use of dimethylzinc, resulting in the formation of the novel tetranuclear products [N Mo(CH3)2(O-t-C4H9) · 1 2py]4 (3) (py = 4-t-butylpyridine). A single-crystal X-ray diffraction study reveals four NMo(CH3)2 units being connected through the nitrogen atoms, thereby forming unsymmetrical, linear MoN-Mo units. The cubane-type zinc complex [CH3ZnO-t-C4H9]4 (4; X-ray diffraction study) is also formed.
AB - Methylation of the nitridomolybdenum(VI) complex NMo(O-t-C4H9)3 2, obtained from NMoCl3· THF (1), is achieved by use of dimethylzinc, resulting in the formation of the novel tetranuclear products [N Mo(CH3)2(O-t-C4H9) · 1 2py]4 (3) (py = 4-t-butylpyridine). A single-crystal X-ray diffraction study reveals four NMo(CH3)2 units being connected through the nitrogen atoms, thereby forming unsymmetrical, linear MoN-Mo units. The cubane-type zinc complex [CH3ZnO-t-C4H9]4 (4; X-ray diffraction study) is also formed.
UR - http://www.scopus.com/inward/record.url?scp=35148853156&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(92)86013-T
DO - 10.1016/0022-328X(92)86013-T
M3 - Article
AN - SCOPUS:35148853156
SN - 0022-328X
VL - 430
SP - C33-C38
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -