TY - JOUR
T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen. CXLIII{star, open} {star, open} CXLII. Mitteilung, siehe Ref. [1].. Indenyltrioxorhenium(VII)
T2 - Organometalloxid mit dynamischer struktur
AU - Herrmann, Wolfgang A.
AU - Kühn, Fritz E.
AU - Romão, Carlos C.
PY - 1995/3/8
Y1 - 1995/3/8
N2 - Indenyltrioxorhenium(VII), (C9H7)ReO3, was synthesized from Re2O7 and (indenyl)tris(n-butyl)tin. It is a moisture- and temperature-sensitive compound (dec. -30°C), the structure of which adopts η1-coordination of the organic ligand. According to 1H NMR studies, a haptotropic structural rearrangement occurs at >-25°C in solution (1,3-shift mechanism). Decomposition studies show a concentration decay of the title compound in anhydrous solution, with formation ReO3 and indene.
AB - Indenyltrioxorhenium(VII), (C9H7)ReO3, was synthesized from Re2O7 and (indenyl)tris(n-butyl)tin. It is a moisture- and temperature-sensitive compound (dec. -30°C), the structure of which adopts η1-coordination of the organic ligand. According to 1H NMR studies, a haptotropic structural rearrangement occurs at >-25°C in solution (1,3-shift mechanism). Decomposition studies show a concentration decay of the title compound in anhydrous solution, with formation ReO3 and indene.
UR - https://www.scopus.com/pages/publications/0002775711
U2 - 10.1016/0022-328X(94)05211-S
DO - 10.1016/0022-328X(94)05211-S
M3 - Artikel
AN - SCOPUS:0002775711
SN - 0022-328X
VL - 489
SP - C56-C59
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -